화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.67, 407-416, November, 2018
DOI10.1016/j.jiec.2018.07.015  Export Citation
Nanocomposite SiEA-KNiFe sorbent - Complete solution from synthesis through radiocesium sorption to vitrification using the sol.gel method
Dagmara Chmielewska†, Małgorzata Siwek1, Danuta Wawszczak, Marek Henczka1, Bo_zena Sartowska, Wojciech Starosta, and Jakub Dudek
  • Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland
  • 1Faculty of Chemical and Process Engineering, Warsaw University of Technology, Warynskiego 1, 00-645 Warsaw, Poland
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This study presents a novel complete solution starting with a synthesis of silica modified with potassiumnickel hexacyanoferrate and ethanolamine (SiEA-KNiFe) sorbent through radiocesium sorption in different process configurations and moving on to the vitrification of the spent sorbent, using the sol.gel method. The experimental data for deionized water solution, as well as seawater solution, correlates strongly with the Langmuir isotherm model. Moreover, the study also presents a method for spent sorbent solidification in the glass matrix. The cesium leaching test confirmed that spent sorbent can be stably bound in the glass matrix after radionuclide removal.
Keywords:Cesium;Sorption;Batch;Column;Vitrification;Leaching
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