4-Hexylresorcinol sensor development based on wet-chemically prepared Co3O4@Er2O3 nanorods: A practical approach

Tahir Ali Sheikh; Mohammed M. Rahman; Abdullah M. Asiri; Hadi M. Marwani; Md. Rabiul Awual

Journal of Industrial and Engineering Chemistry, Vol.66, 446-455, October, 2018

DOI10.1016/j.jiec.2018.06.012 Export Citation

4-Hexylresorcinol sensor development based on wet-chemically prepared Co3O4@Er2O3 nanorods: A practical approach

Tahir Ali Sheikh^{1, 2}, Mohammed M. Rahman^{1, 2, †}, Abdullah M. Asiri^{1, 2}, Hadi M. Marwani^{1, 2}, and Md. Rabiul Awual³

¹Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
²Center of Excellence for Advanced Materials Research, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
³Depertment of Chemical Engineering, Curtin University, GPO Box U1987, Perth, WA 6845, Australia

E-mail:

In this approach, Co3O4@Er2O3 nanorods (NRs) were prepared by a wet-chemical method using reducing agents in alkaline medium. The resulting nanoparticles were characterized in details by UV/Vis and FT-IR spectroscopy, X-ray powder diffraction, Elemental dispersive analysis (EDS) coupled with field-emission scanning electron microscopy (FESEM). Co3O4@Er2O3NRs were deposited on a glassy carbon electrode (GCE) to give a selective sensor with a fast response toward 4-hexyl resorcinol (4-HR) in phosphate buffer phase (PBS) by electrochemical approach. The 4-HR sensor also displays good sensitivity, large linear dynamic range, lowest detection limit, and long-term stability, and enhanced electrochemical response. The calibration plot is linear over the 0.1 nM.0.01 M 4-HR concentration range. The sensitivity is ~14.765 μAμM-1cm-2, and the detection limit is 64.29 pM (signal-to-noise ratio, at a SNR of 3). We also discuss possible future prospective uses of this doped metal oxide semiconductor nanomaterial in terms of chemical sensing.

Keywords:Co3O4@Er2O3 nanorods;4-Hexyl resorcinol;Sensitivity;Glassy carbon electrode;Environmental safety

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[1] Hussain I, Singh NB, Singh A, Singh H, Singh SC, Biotechnol. Lett., 38(4), 545 (2016)

[2] Salata O, J. Nanobiotechnol., 2, 3 (2004)

[3] Sozer N, Kokini JL, Trends Biotechnol., 27, 82 (2009)

[4] Moon SH, Jin WJ, Kim TR, Hahm HS, Cho BW, Kim MS, J. Ind. Eng. Chem., 11(4), 594 (2005)

[5] Mutyala S, Mathiyarasu J, Sens. Actuators B-Chem., 210, 692 (2015)

[6] Umar A, Rahman MM, Kim SH, Hahn YB, Chem. Commun., 166 (2008).

[7] Sosa IO, Noguez C, Barrera RG, J. Phys. Chem. B, 107(26), 6269 (2003)

[8] Maaz K, Mumtaz A, Hasanain SK, Ceylan A, J. Magn. Magn. Mater., 308, 289 (2007)

[9] Li JH, Hong RY, Li MY, Li HZ, Zheng Y, Ding J, Prog. Org. Coat., 64, 504 (2009)

[10] Veith GM, Lupini AR, Rashkeev S, Pennycook SJ, Mullins DR, Schwartz V, Bridges CA, Dudney NJ, J. Catal., 262(1), 92 (2009)

[11] Qamar MT, Aslam M, Ismail IMI, Salah N, Hameed A, ACS Appl. Mater. Interfaces, 7, 8757 (2015)

[12] Kerli S, Mod. Phys. Lett. B, 30, 165034 (2016)

[13] Wen Z, Zhu L, Mei W, Li Y, Hu L, Sun L, Wan W, Ye Z, J. Mater. Chem. A, 1, 7511 (2013)

[14] Wen Z, Chen J, Yeh MH, Guo H, Li Z, Fan X, Zhang T, Zhu L, Wang ZL, Nano Energy, 16, 38 (2015)

[15] Wen Z, Zhu L, Li Y, Zhang Z, Ye Z, Sens. Actuators B-Chem., 203, 873 (2014)

[16] Wen Z, Zhu L, Mei W, Hu L, Li Y, Sun L, Cai H, Ye Z, Sens. Actuators B-Chem., 186, 172 (2013)

[17] Svegl F, Orel B, Grabec-Svegl I, Kaucic V, Electrochim. Acta, 45(25-26), 4359 (2000)

[18] Ryu J, Kim SW, Kang K, Park CB, ACS Nano, 4, 159 (2010)

[19] Gao J, Gu H, Xu B, Accounts Chem. Res., 42, 1097 (2009)

[20] Michałowicz J, Duda ROW, Water, Air, Soil Pollut., 164, 205 (2005)

[21] Kachoosangi RT, Wildgoose GG, Compton RG, Electroanalysis, 20, 1714 (2008)

[22] Nickel JC, J. Urol., 173, 21 (2005)

[23] Musto JD, Sane JN, Warner VD, J. Pharm. Sci., 68, 240 (1979)

[24] Ahrenfeldt RH, Arch. Int. Pharmacodyn. Ther., 93, 33 (1953)

[25] Manceau JN, Rev. Do Servico Espec. Saude Publica, 8, 205 (1955)

[26] Montero P, Martinez-Alvarez O, del M. Gomez-Guillen C, J. Food Sci., 69 (2004)

[27] Luo Y, Barbosa-Canovas GV, Rev. Agaroquim. Y Tecnol. Aliment., 2, 315 (1996)

[28] Kim YH, Kim JM, Lee JS, Gang SR, Lim HS, Kim M, Lee OH, Food Chem., 190, 1086 (2016)

[29] Pel E, Bordin G, Rodriguez AR, J. Liq. Chromatogr. Relat. Technol., 21, 883 (1998)

[30] Johnson KT, Lemmo J, Southall M, Wen P, High-clarity aqueous concentrates of 4-hexylresorcinol, 2011. https://www.google.com/patents/US8084504.

[31] Hexylresorcinol, (n.d.). https://www.truthinaging.com/ingredients/hexylres-orcinol. (Accessed 5 December 2017).

[32] National Institute for Occupational Safety and Health, NIOSH Pocket Guide to Chemical Hazards, DHHS Publ., pp. 424 2005.

[33] Hahn S, Resorcinol, World Health Organization, 2006.

[34] Lynch BS, Delzell ES, Bechtel DH, Regul. Toxicol. Pharmacol., 36, 198 (2002)

[35] Smallwood AW, Ranieri TL, Satzger RD, J. AOAC Int., 81, 488 (1997)

[36] Li XQ, Zhang F, Sun YY, Yong W, Chu XG, Fang YY, Zweigenbaum J, Anal. Chim. Acta, 608, 165 (2008)

[37] Robbins BH, Wesson LG, J. Pharmacol. Exp. Ther., 43, 335 (1931)

[38] Afkhami A, Khatami HA, J. Anal. Chem., 56, 429 (2001)

[39] Zhang D, Peng Y, Qi H, Gao Q, Zhang C, Sens. Actuators B-Chem., 136, 113 (2009)

[40] Tiwari M, Gupta S, Prakash R, RSC Adv., 4, 25675 (2014)

[41] Liao Q, Sun J, Gao L, Colloids Surf. A: Physicochem. Eng. Asp., 312, 160 (2008)

[42] Bayram E, Hoda N, Ayranci E, J. Hazard. Mater., 168(2-3), 1459 (2009)

[43] Rahman MM, Balkhoyor HB, Asiri AM, RSC Adv., 6, 29342 (2016)

[44] Rahman MM, Balkhoyor HB, Asiri AM, J. Environ. Manage., 188, 228 (2017)

[45] Hussain MM, Rahman MM, Asiri AM, Awual MR, RSC Adv., 6, 80511 (2016)

[46] Alrehaily LM, Joseph JM, Biesinger MC, Guzonas DA, Wren JC, Phys. Chem. Chem. Phys., 15, 1014 (2013)

[47] Cheng JP, Chen X, Ma R, Liu F, Zhang XB, Mater. Charact., 62, 775 (2011)

[48] Mohammadi MR, Ghorbani M, Fray DJ, Mater. Sci. Technol., 22, 965 (2006)

[49] Wang XJ, Dong B, Lei MK, J. Sol-Gel Sci. Technol., 39, 307 (2006)

[50] Xu W, Min X, Chen X, Zhu Y, Zhou P, Cui S, Xu S, Tao L, Song H, Sci. Rep., 4, 5087 (2014)

[51] Castaneda-Contreras J, Maranon-Ruiz VF, Meneses-Nava MA, Perez-Ladron de Guevara H, Rojas RAR, Chiu-Zarate R, Rev. Mex. Fisica., 61, 127 (2015)

[52] Kang M, Zhou H, AIMS Biophys., 2, 16 (2015)

[53] Sakamoto T, Matsumura D, Asazawa K, Martinez U, Serov A, Artyushkova K, Atanassov P, Tamura K, Nishihata Y, Tanaka H, Electrochim. Acta., 163, 116 (2015)

[54] Manukyan KV, Cross A, Rouvimov S, Miller J, Mukasyan AS, Wolf EE, Appl. Catal. A: Gen., 476, 47 (2014)

[55] Tamasauskaite-Tamasiunaite L, Rakauskas J, Balciunaote A, Zabielaite A, Vaiciuniene J, Selskis A, Juskenas R, Pakstas V, Norkus E, J. Power Sources, 272, 362 (2014)

[56] Thomas J, Radhika S, Yoon M, J. Mol. Catal. A-Chem., 411, 146 (2016)

[57] Hadjltaief HB, Sdiri A, Ltaief W, Da Costa P, Galvez ME, Zina MB, Comptes Rendus Chim. (2017).