화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 209-220, October, 2018
DOI10.1016/j.jiec.2018.05.032  Export Citation
Polyelectrolyte nanoparticles based thin-film nanocomposite (TFN) membranes for amino acids separation
Yan-Li Ji1, 2, Wei-Jie Qian1, Quan-Fu An3, †, Kueir-Rarn Lee4, and Cong-Jie Gao1, 2
  • 1Center for Membrane and Water Science & Technology, Ocean College, Zhejiang University of Technology, Hangzhou 310014, China
  • 2Collaborative Innovation Center of Membrane Separation and Water Treatment of Zhejiang Province, Hangzhou 310014, China
  • 3Beijing Key Laboratory for Green Catalysis and Separation, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • 4dR&D Center for Membrane Technology, Department of Chemical Engineering, Chung Yuan University, Chung-Li 32023, Taiwan
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We have designed a novel type of thin-film nanocomposite (TFN) membranes with embedded polyelectrolyte nanoparticles (PNPs) and investigated their applicability in the separation of amino acids. PNP particles were mixed with piperazine (PIP) and interfacial polymerized with trimesoyl chloride (TMC), allowing for simultaneous improvement in water permeability, amino acid selectivity, and antifouling property. Separation performance could be conveniently tuned by modulating the chemical structure of PNPs and their content in TFN membranes, as well as adjusting the feed pH value. This work would promote the application of polyelectrolyte nanoparticles based TFN membranes in the separation and purification of amino acids.
Keywords:Polyelectrolyte nanoparticles;Nanocomposite membranes;Polyamide;Nanofiltration;Amino acid separation
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