화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 86-93, October, 2018
DOI10.1016/j.jiec.2018.05.004  Export Citation
Use of grape seed as reductant for leaching of cobalt from spent lithium-ion batteries
Yingjie Zhang†, Qi Meng, Peng Dong†, Jianguo Duan, and Yan Lin
  • National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
E-mail:,
The grape seed was novelly used as reductant for leaching of spent LiCoO2 material, which is idea of “waste + waste → resources”. About 92% Co and 99% Li could be leached under the optimized conditions of grape seed 0.6 g/g, malic acid 1.5 mol/L, 180 min, 80 °C, and slurry density 20 g/L. The catechin, EC and EGCG contained in grape seed could be employed as efficient reductants during leaching. The leaching process is controlled by combination of surface chemical reaction and diffusion with apparent activation energy of 11.96 kJ/mol, which is related to the form of Co(OH)3.
Keywords:Spent lithium-ion batteries;Leaching;Grape seed;Kinetics;XPS
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