Development of a hydrometallurgical route for the recovery of molybdenum from spent hydrodesulphurization catalyst using Cyphos IL 104

Harshit Mahandra; Rashmi Singh; Bina Gupta

Journal of Industrial and Engineering Chemistry, Vol.65, 213-223, September, 2018

DOI10.1016/j.jiec.2018.04.031 Export Citation

Development of a hydrometallurgical route for the recovery of molybdenum from spent hydrodesulphurization catalyst using Cyphos IL 104

Harshit Mahandra, Rashmi Singh, and Bina Gupta^†

Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India

E-mail:

This study investigates the partition of molybdenum in presence of hydrochloric acid with Cyphos IL 104 diluted in toluene and recovery of molybdenum from spent hydrodesulphurization catalyst. Effect of various parameters has been estimated. Recyclability and loading capacity have been assessed. Influence of temperature confirmed the process to be endothermic in nature. Binary separations of molybdenum have been achieved with high separation factors. Optimized conditions have been fused for molybdenum recovery from spent hydrodesulphurization catalyst leach liquor. McCabe.Thiele diagrams have been constructed. Molybdenum is finally obtained as MoO3 from the strip solution and characterized by XRD, FE-SEM and EDX techniques.

Keywords:Cyphos IL 104;Molybdenum;Spent hydrodesulphurization catalyst;Recovery

[References]

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Elwell WT, Wood DF, Analytical Chemistry of Molybdenum and Tungsten, first ed., Pergamon Press Ltd., New York, 1971.
Li Z, Chen M, Zhang Q, Liu X, Saito F, Waste Manage., 60, 734 (2017)
Zhang XY, Ning PG, Cao HB, Zhang Y, Ind. Eng. Chem. Res., 55(5), 1427 (2016)
Ojo JO, Sep. Sci. Technol., 48(10), 1577 (2013)
Padhan E, Sarangi K, Int. J. Miner. Process., 127, 52 (2014)
Saberyan K, Maragheh MG, Ashtari P, Alamdari SK, Miner. Eng., 16(4), 391 (2003)
Knyaz’kina OV, Kuznetsova GG, Travkin VF, Vol’dman GM, Glubokov YM, Russ. J. Non Ferrous Met., 51, 451 (2011)
Quijada-Maldonado E, Torres MJ, Romero J, Sep. Purif. Technol., 177, 200 (2017)
Park KH, Kim HI, Parhi PK, Sep. Purif. Technol., 74(3), 294 (2010)
Rout PC, Sarangi K, Hydrometallurgy, 133, 149 (2013)
Lasheen TA, Ibrahim ME, Hassib HB, Helal AS, Hydrometallurgy, 146, 175 (2014)
Wejman-Gibas K, Wieszczycka K, Wojciechowska A, Ochromowicz K, Pohl P, Sep. Purif. Technol., 158, 71 (2016)
Kim HI, Lee KW, Mishra D, Yi KM, Hong JH, Jun MK, Park HK, J. Ind. Eng. Chem., 21, 1265 (2015)
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Marie C, Vanel V, Watanabe S, Duchesne MT, Zorz N, Berthon L, Solvent Extr. Ion Exch., 34, 407 (2016)
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Regel-Rosocka M, Sep. Purif. Technol., 66(1), 19 (2009)
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Kogelnig D, Stojanovic A, Jirsa F, Korner W, Krachler R, Keppler BK, Sep. Purif. Technol., 72(1), 56 (2010)
Cieszynska A, Wisniewski M, Hydrometallurgy, 113-114, 79 (2012)
Bonggotgetsakul YYN, Cattrall RW, Kolev SD, Membranes, 5, 903 (2015)
Pospiech B, Hydrometallurgy, 154, 88 (2015)
Zhu Z, Tulpatowicz K, Pranolo Y, Cheng CY, Hydrometallurgy, 154, 72 (2015)
Olazabal MA, Orive MM, Fernandez LA, Madariaga JM, Solvent Extr. Ion Exch., 10, 623 (1992)
Bal Y, Ba KE, Cote G, Lallam A, Hydrometallurgy, 75, 123 (2004)
Cholico-Gonzalez D, Avila-Rodriguez M, Cote G, Chagnes A, J. Mol. Liq., 187, 165 (2013)
Saily A, Tandon SN, Chem. Anal. (Warsaw), 42, 57 (1997)
Banda R, Nguyen TH, Sohn SH, Lee MS, Hydrometallurgy, 133, 161 (2013)
Mahandra H, Singh R, Gupta B, J. Clean Prod., 172, 133 (2017)

[1] Noronha LE, Kamble GS, Kolekar SS, Anuse MA, Int. J. Chem. Sci. Technol., 3, 15 (2013)

[2] Elwell WT, Wood DF, Analytical Chemistry of Molybdenum and Tungsten, first ed., Pergamon Press Ltd., New York, 1971.

[3] Li Z, Chen M, Zhang Q, Liu X, Saito F, Waste Manage., 60, 734 (2017)

[4] Zhang XY, Ning PG, Cao HB, Zhang Y, Ind. Eng. Chem. Res., 55(5), 1427 (2016)

[5] Ojo JO, Sep. Sci. Technol., 48(10), 1577 (2013)

[6] Padhan E, Sarangi K, Int. J. Miner. Process., 127, 52 (2014)

[7] Saberyan K, Maragheh MG, Ashtari P, Alamdari SK, Miner. Eng., 16(4), 391 (2003)

[8] Knyaz’kina OV, Kuznetsova GG, Travkin VF, Vol’dman GM, Glubokov YM, Russ. J. Non Ferrous Met., 51, 451 (2011)

[9] Quijada-Maldonado E, Torres MJ, Romero J, Sep. Purif. Technol., 177, 200 (2017)

[10] Park KH, Kim HI, Parhi PK, Sep. Purif. Technol., 74(3), 294 (2010)

[11] Rout PC, Sarangi K, Hydrometallurgy, 133, 149 (2013)

[12] Lasheen TA, Ibrahim ME, Hassib HB, Helal AS, Hydrometallurgy, 146, 175 (2014)

[13] Wejman-Gibas K, Wieszczycka K, Wojciechowska A, Ochromowicz K, Pohl P, Sep. Purif. Technol., 158, 71 (2016)

[14] Kim HI, Lee KW, Mishra D, Yi KM, Hong JH, Jun MK, Park HK, J. Ind. Eng. Chem., 21, 1265 (2015)

[15] Sahu KK, Agrawal A, Mishra D, J. Environ. Manage., 125, 68 (2013)

[16] Parhi PK, Park KH, Kim HI, Park JT, Hydrometallurgy, 105, 195 (2011)

[17] Marie C, Vanel V, Watanabe S, Duchesne MT, Zorz N, Berthon L, Solvent Extr. Ion Exch., 34, 407 (2016)

[18] Kumari A, Sinha MK, Sahu SK, Pandey BD, Solvent Extr. Ion Exch., 34, 469 (2016)

[19] Wilson AM, Bailey PJ, Tasker PA, Turkington JR, Grant RA, Love JB, Chem. Soc. Rev., 43, 123 (2014)

[20] Singh R, Mahandra H, Gupta B, Waste Manag., 67, 240 (2017)

[21] Singh R, Mahandra H, Gupta B, Hydrometallurgy, 172, 11 (2017)

[22] Mahandra H, Singh R, Gupta B, Sep. Purif. Technol., 177, 281 (2017)

[23] Wellens S, Goovaerts R, Moller C, Luyten J, Thijs B, Binnemans K, Green Chem., 15, 3160 (2013)

[24] Regel-Rosocka M, Sep. Purif. Technol., 66(1), 19 (2009)

[25] Gallardo V, Navarro R, Saucedo I, Avila M, Guibal E, Sep. Sci. Technol., 43(9-10), 2434 (2008)

[26] Vincent T, Parodi A, Guibal E, Sep. Purif. Technol., 62(2), 470 (2008)

[27] Kogelnig D, Stojanovic A, Jirsa F, Korner W, Krachler R, Keppler BK, Sep. Purif. Technol., 72(1), 56 (2010)

[28] Cieszynska A, Wisniewski M, Hydrometallurgy, 113-114, 79 (2012)

[29] Bonggotgetsakul YYN, Cattrall RW, Kolev SD, Membranes, 5, 903 (2015)

[30] Pospiech B, Hydrometallurgy, 154, 88 (2015)

[31] Zhu Z, Tulpatowicz K, Pranolo Y, Cheng CY, Hydrometallurgy, 154, 72 (2015)

[32] Olazabal MA, Orive MM, Fernandez LA, Madariaga JM, Solvent Extr. Ion Exch., 10, 623 (1992)

[33] Bal Y, Ba KE, Cote G, Lallam A, Hydrometallurgy, 75, 123 (2004)

[34] Cholico-Gonzalez D, Avila-Rodriguez M, Cote G, Chagnes A, J. Mol. Liq., 187, 165 (2013)

[35] Saily A, Tandon SN, Chem. Anal. (Warsaw), 42, 57 (1997)

[36] Banda R, Nguyen TH, Sohn SH, Lee MS, Hydrometallurgy, 133, 161 (2013)

[37] Mahandra H, Singh R, Gupta B, J. Clean Prod., 172, 133 (2017)