Constrained growth of solid amino alkyl siloxane (an organic-inorganic hybrid): The ultimate selective sorbent for CO2

Rajangam Vinodh; Aziz Abidov; Muthiahpillai Palanichamy; Wang Seog Cha; Hyun Tae Jang

Journal of Industrial and Engineering Chemistry, Vol.65, 156-166, September, 2018

DOI10.1016/j.jiec.2018.04.024 Export Citation

Constrained growth of solid amino alkyl siloxane (an organic-inorganic hybrid): The ultimate selective sorbent for CO2

Rajangam Vinodh^{1, 2}, Aziz Abidov^{1, 2}, Muthiahpillai Palanichamy^{1, 2}, Wang Seog Cha^{2, 3}, and Hyun Tae Jang^{1, 2, †}

¹Department of Chemical Engineering, Hanseo University, Seosan 31962, South Korea
²Korea Carbon Capture and Sequestration R & D Centre, 46, Hanseo 1-ro, Haemi-myun, Seosan-si 31962, Chungcheongnam-do, South Korea
³School of Civil and Environmental Engineering, Kunsan National University, Gunsan-si, 54150, South Korea

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Herein, we report a solid matrix of amino alkyl siloxane of porous nature with alkyl groups thoroughly distributed in the matrix by constrained growth technique; this sorbent is ideal for CO2 sorption. The sorbent exhibits higher sorption (4 mmol CO2/g), and selectivity to CO2. It is enriched with voids, and exhibits adequate thermal stability. Adsorption occurred below 100 °C, while desorption occurred between 100 and 200 °C. When the sorbent underwent both sorption and desorption of CO2, a sharp enthalpy change was observed; such an enthalpy change is a crucial characteristic of cyclic sorption desorption (CSD).

Keywords:Organic inorganic hybrid;Aminoalkyl siloxane;CO2 capture;APTES;TEOS

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[2] Rochelle GT, Science, 325, 1652 (2009)

[3] Bottoms RR, United States patent US 1,783,901 (1930).

[4] Oko E, Wang M, Joel AS, Int. J. Coal Sci. Technol., 4(1), 5 (2017)

[5] Miyamoto M, Fujiokax Y, Yogo K, J. Mater. Chem., 22, 20186 (2012)

[6] Balsamo M, Budinova T, Erto A, Lancia A, Petrova B, Petrov N, Tsyntsarski B, Sep. Purif. Technol., 116, 214 (2013)

[7] Li L, Li Y, Wen X, Wang F, Zhao N, Xiao FK, Wei W, Sun YH, Energy Fuels, 25(8), 3835 (2011)

[8] Srivastava HK, Sastry GN, J. Phys. Chem. A, 115(26), 7633 (2011)

[9] Yang DA, Cho HY, Kim J, Yang ST, Ahn WS, Energy Environ. Sci., 5, 6465 (2012)

[10] Olajire AA, Greenhouse Gas Sci. Technol., 7, 399 (2017)

[11] Unveren EE, Monkul BO, Sarıoglan S, Karademir N, Alper E, Petroleum, 3, 37 (2017)

[12] Veawab A, Tontiwachwuthikul P, Chakma A, Ind. Eng. Chem. Res., 38(10), 3917 (1999)

[13] Dawson R, Cooper AI, Adams DJ, Polym. Int., 62, 345 (2013)

[14] Duke MC, Ladewig B, Smart S, Rudolph V, da Costa JCD, Front. Chem. Eng. China, 4, 184 (2010)

[15] Samanta A, Zhao A, Shimizu GKH, Sarkar P, Gupta R, Ind. Eng. Chem. Res., 51(4), 1438 (2012)

[16] Goto K, Yogo K, Higashii T, Appl. Energy, 111, 710 (2013)

[17] Qian Y, Delgado JDLP, Veneman R, Brilman DWF, Ind. Eng. Chem. Res., 56(12), 3259 (2017)

[18] Mayorga SG, Weigel SJ, Gaffney TR, Brzozowski JR, US Patent 6280503 B1 (2001).

[19] Siriwardane RV, Robinson C, Shen M, Simonyi T, Energy Fuels, 21(4), 2088 (2007)

[20] Chen C, Kim J, Ahn WS, Korean J. Chem. Eng., 31(11), 1919 (2014)

[21] Zhang G, Zhao P, Xu Y, J. Ind. Eng. Chem., 54, 59 (2017)

[22] Frank H, Maximilian C, Jurgen M, Michael F, Angew. Chem.-Int. Edit., 45, 3216 (2006)

[23] Cheng-Hsiu Y, Chih-Hung H, Chung-Sung T, Aerosol Air Qual. Res., 12, 745 (2012)

[24] Yoshiyuki S, Tsuyoshi I, Kazuyuki K, J. Mater. Chem., 7, 53 (1997)

[25] Ma XL, Wang XX, Song CS, J. Am. Chem. Soc., 131(16), 5777 (2009)

[26] Xu XC, Song CS, Miller BG, Scaroni AW, Fuel Process. Technol., 86(14-15), 1457 (2005)

[27] Zhang ZH, Ma XL, Wang DX, Song CS, Wang YG, AIChE J., 58(8), 2495 (2012)

[28] Leal O, Bolivar C, Ovalles C, Garcia J, Espidel Y, Inorg. Chim. Acta., 240, 183 (1995)

[29] Kishor R, Ghoshal AK, Ind. Eng. Chem. Res., 56(20), 6078 (2017)

[30] Goeppert A, Meth S, Prakash GKS, Olah GA, Energy Environ. Sci., 3, 949 (2010)

[31] Macquarrie DJ, Jackson DB, Chem. Commun., 1781 (1997)

[32] Macquarrie DJ, Jackson DB, Tailland S, Utting KA, J. Mater. Chem., 11, 1843 (2001)

[33] Corma A, Iborra S, Rodriguez I, Iglesias M, Sanchez F, Catal. Lett., 82(3-4), 237 (2002)