A series of solid amine adsorbents were prepared by the template method with ion-exchange resin (D001) as the carrier and polyethyleneimine (PEI) as the modifier. The absorbents were characterized by energy disperse spectroscopy (EDS), scanning electron microscope (SEM), N-2 adsorption-desorption, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) techniques. The effects of PEI loading, adsorption temperature and influent velocities on CO2 adsorption capacity in a fixed-bed reactor were investigated. The results show that the solid amine adsorbent prepared by the template method had a better PEI dispersion, stability and CO2 adsorption capacity. The maximum CO2 adsorption capacity was 3.98mmolg(-1) when PEI loading was 30%, the adsorption temperature was 65 degrees C and the influent velocity was 40mLmin(-1). The CO2 adsorption capacity decreased only by 9.50% after 10 cycles of adsorption-desorption tests. The study of kinetics indicates that both chemical adsorption and physical adsorption occurred in the CO2 adsorption process. The CO2 adsorption process included fast breakthrough adsorption and gradually approaching equilibrium stage. The particle internal diffusion process was the control step for CO2 adsorption.