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Journal of the Electrochemical Society, Vol.165, No.5, E236-E244, 2018
The Enhancement of Ion Transport in an Electrochemical Cell Using High Frequency Vibration for the Electropolishing of Copper
A previous experiment showed that the rate of the electropolishing of a copper anode may be increased by twofold when generating a 60 KHz to 1.7MHz frequency vibration in the anode. In this work we use theory to elucidate the mechanisms by which the vibration may enhance the transport of ions in the electrolyte solution and support the formation of dents in the anode, which was observed in experiment. We find that in the limit of weak ion convection the transport of ions mainly supports the formation of dents in the anode. However, in the limit of prominent ion convection we find an appreciable contribution of the vibration to the efficiency of the electropolishing process, in accordance with the previous experimental findings. The contribution of the vibration to ion transport is given by 2 root PeDkC(s)/pi root pi, in which the Peclet number, Pe, quantifies the ratio between the convective and diffusive fluxes of ions, and D, k, and Cs are the diffusion coefficient of the ions, the wavenumber of the vibration, and the solubility limit of the ions in the electrolyte. (C) The Author(s) 2018. Published by ECS.