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Journal of the Electrochemical Society, Vol.165, No.2, C1-C10, 2018
Corrosion Mechanisms in Dissimilar AZ31/AZ80 Friction Stir Welds
Corrosion of dissimilar friction stir welds (FSW) made inAZ31/AZ80 magnesium alloyswas investigated using the scanning reference electrode technique (SRET), and microcapillary polarization technique, complemented by optical and SEM/EDX microscopy. The corrosion rate of the base metals along with the welded specimen was estimated by mass loss testing. The stir zone material in both alloys showed a higher corrosion potential than the base metal due to the partial dissolution of beta-Mg17Al12 and Al-Mn particles. The basic corrosion mechanism in dissimilar welds was determined to be different from that of a similar joint. The corrosion behavior of the dissimilar FSW joint was governed by the galvanic coupling of the two alloys, and not by the microstructural evolution occurring during the welding process. The corrosion behavior of the joint was governed by the galvanic coupling between the alpha-Mg matrix in AZ31 and the Al-rich intermetallics in AZ80. The welded specimens exhibited the highest corrosion rate, while AZ80 was the most corrosion resistant material. (C) The Author(s) 2018. Published by ECS.