It has been shown recently that the overpotential originating from ionic conduction of alkali-ions through the inner dense solidelectrolyte interphase (SEI) is strongly non-linear. An empirical equation was proposed to merge the measured resistances from both galvanostatic cycling (GS) and electrochemical impedance spectroscopy (EIS) at 25 degrees C. Here, this analysis is extended to the full temperature range of batteries from -40 degrees C to +80 degrees C for Li, Na, K and Rb-metal electrodes in carbonate electrolytes. Two different transport mechanisms are found. The first one conducts alkali-ions at all measured temperatures. The second transport mechanism conducts ions for all seven measured Li-ion electrolytes and one out of four Na-ion electrolytes; however, only above a certain critical temperature TC. At TC a phase transition is observed switching-off the more efficient transport mechanism and leaving only the general ion conduction mechanism. The associated overpotentials increase rapidly below TC depending on alkali-ion, salt and solvent and become a limiting factor during galvanostatic operation of all Li-ion electrolytes at low temperature. In general, the current analysis merges the SEI resistances measured by EIS ranging from 26 Omega cm(2) for the best Li up to 292 M Omega cm(2) for Rb electrodes to its galvanostatic response over seven orders of magnitude. The determined critical temperatures are between 0-25 degrees C for the tested Li and above 50 degrees C for Na electrolytes. (C) The Author(s) 2018. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License.