Journal of the American Ceramic Society, Vol.101, No.7, 2689-2694, 2018
Preparation and photoluminescence enhancement of Au nanoparticles embedded LaPO4:Eu3+ inverse opals
In this work, we present a facile preparation approach of Au nanoparticles embedded LaPO4:Eu3+ inverse opal photonic crystals. In the typical preparation process, the transparent LaPO4:Eu3+ sol including HAuCI4 was infiltrated into the opal templates. After the sintering, the 10-20 nm Au nanoparticles were formed in the interior of nano-sized wall of LaPO4:Eu3+ inverse opal and the Au nanoparticles embedded LaPO4:Eu3+ inverse opals were obtained. The luminescence of Au nanoparticles embedded LaPO4:Eu3+ inverse opal was investigated. The emission peaks located at the 593 ((D0F1)-D-5-F-7), 618 ((D0F2)-D-5-F-7) and 698 nm ((D0F4)-D-5-F-7) from Eu3+ ions were observed. The 593, 618, and 698 nm emissions of Au nanoparticles embedded LaPO4:Eu3+ inverse opals were enhanced in contrast to these of LaPO4:Eu3+ inverse opal without the Au nanoparticles, which is from the excitation field enhancement caused by the localized surface plasmon resonance of Au nanoparticles.