Journal of the American Ceramic Society, Vol.101, No.8, 3662-3673, 2018
Ion irradiation effect on spark plasma sintered silicon carbide ceramics with nanostructured ferritic alloy aid
Silicon carbide (SiC) is a promising material with excellent chemical and physical performance under irradiation for advanced nuclear applications. The addition of nanostructured ferritic alloy (NFA) has been proven beneficial for the densification of SiC ceramics based on our previous work. To understand their microstructural evolution and irradiation resistance, spark plasma sintered (SPSed) SiC ceramics with and without NFA aid (0vol% NFA-100vol% SiC, 2.5vol% NFA-97.5vol% SiC, and 5vol% NFA-95vol% SiC) were exposed to 5MeV Si++ irradiation. The ion irradiation strongly modifies the surface morphology with isolated sand dune shaped structures, which can be explained by the Bradley-Harper (B-H) theory. SRIM simulation for both the pure SiC and NFA-SiC predicts similar surface damage of similar to 45dpa and peak damage of similar to 790dpa at similar to 2.0m depth. For the actual samples, the SiC matrix is completely amorphous up to similar to 2.2m thickness (from the surface dune valley to the amorphous layer boundary), which is consistent with the SRIM predicted depth of similar to 2.3m. Reaction product (Fe,Cr)(3)Si in the NFA-SiC samples maintains a crystalline structure with dislocation loops. A defect rate model is applied to understand the fundamental difference in ion irradiation resistance between SiC and (Fe,Cr)(3)Si.
Keywords:defects;microstructure;nanostructured ferritic alloy aid;Si++ ion irradiation;silicon carbide