A spiral-wound membrane module comprising face compression "O" rings for effective seal of gases was developed, including a spiral-wound membrane element, Plexiglas fiber-reinforced plastic tube, and membrane housing. The spiral-wound membrane modules demonstrated essentially no leakage. The concentration polarization phenomenon was observed at a dry feed gas flow rate of less than 1000 sccm before humidification. Hence, the performances of the spiral-wound membrane modules were evaluated using both dry feed and sweep gas flow rates each at 1000 sccm before humidification at the typical flue gas temperature of 57 degrees C. The feed and sweep gas pressures were at 1.5 and 1 psig, respectively. By using either a simulated flue gas or an actual flue gas, the spiral-wound membrane modules showed similar performance results with a CO2 permeance of greater than 800 GPU and a CO2/N-2 selectivity of more than 140, which were essentially identical to the results obtained from the flat-sheet membrane used for the module fabrication and tested in laboratory with the simulated flue gas. The pressure drops of the modules were satisfactory, i.e., less than 1.5 psi/m. During the field test using the actual flue gas at the National Carbon Capture Center in Wilsonville, Alabama, the performances of the modules revealed some unexpected issues including the feed spacer indentations on the membrane selective layer and the leakage at glue lines. These issues were resolved by improving the spiral-wound membrane module fabrication using a smoother feed spacer and a longer glue curing time. The field test results of the modules have shown their good potential for the post-combustion CO2 capture from coal-fired power plants.