Journal of Chemical Thermodynamics, Vol.124, 149-152, 2018
The isothermal compressibility and surface tension product of room temperature ionic liquids
The isothermal compressibilities, kappa(T), and surface tensions, sigma, of room temperature ionic liquids (RTILs) were obtained from the literature. The products, kappa(T)sigma, were compared, in analogy with high-melting ionic liquids (molten salts) and liquid metals, with expectations from the scaled particle theory, the correlation lengths, and the dependence on the cohesive energy density, but poor agreement was found. This behavior is ascribed to the 'loose' packing of the ions in the RTILs, due to the large, generally non-spherical ions making up these ionic liquids. (C) 2018 Elsevier Ltd.
Keywords:Room temperature ionic liquids;Isothermal compressibility;Surface tension;Cohesive energy density;Internal pressure