Encapsulation of fullerene C60 in CD-MOF was achieved by crystallization from the C60/gamma-CD complex in KOH solution. C60 was located in hydrophobic nanopores composed of a pair of gamma-CD tori, whereas hydrophilic porphyrin (TCPP) was located in the spherical nanopores at the center of the (gamma-CD)(6) unit. The isolated C60 and TCPP molecules in CD-MOF emitted green and orange fluorescence in the solid state, respectively. The fluorescence intensity of the C60/TCPP/CD-MOF was greatly weakened compared to that of TCPP/CD-MOF due to electron injection from the excited state of TCPP to C60.