The effects of ion -exchangeable K+ and Ca2+ on rice husk pyrolysis, with a focus on the yields and properties of the gas liquid solid products, and their pyrolysis kinetic characteristics, were investigated by thermogravimetry/Fourier-transform infrared spectroscopy and a laboratory-scale fixed-bed reactor. The results indicated that the pyrolysis gas and char yields increased, and the tar yield decreased, with increasing concentrations of K+/Ca2+ in the rice husks. Compared with that of 340 degrees C for H-form rice husks, the maximum weight loss temperature decreased by more than 25 degrees C for the 2.0 wt% K-loaded sample, and increased to 360 degrees C for the 0.2 wt% Ca-loaded one. K+ (2.0 wt%) lowered the first-order activation energy by 18 kJ/mol, and Ca2+ (<0.1 wt%) was more reactive in pyrolysis. The K+/Ca2+ ratio affected the amounts of pyrolysis gases, but not the species, and their presence increased the amount of aromatic C=C structures and surface C=O groups in the biochar. Catalysis with K+/Ca2+ transformed heavy pyrolysis tar compounds into small-molecule ones. (C) 2018 Elsevier Ltd. All rights reserved.