The simple assembling process and lower manufacturing cost are crucial for wide application of perovskite solar cells. In this work, we report an efficient interface passivation strategy for preparing high-performance planar perovskite solar cells, which does not require well-controlled moisture and oxygen atmosphere. A NH4F solution-based additive is introduced to passivated TiO2 electron transfer layer, which offers reduction of oxygen-induced defects and residual surface hydroxyl groups, and lower trap state level. Using a typical planar structure of FTO/NH4F-TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au, the champion device achieves a power conversion efficiency of 15.61%. After 28-day durability test, the device with NH4F-treated TiO2 storing in air without any encapsulation exhibits a little efficiency loss (<10%). Our work demonstrates a generic approach to develop air-processed efficient planar perovskite solar cells by interface engineering for future commercialization. (C) 2018 Elsevier Ltd. All rights reserved.