화학공학소재연구정보센터
Chemical Physics Letters, Vol.703, 63-71, 2018
Effects of solvent quality on contact formation dynamics of polymer chain
We investigate the interplay effects of internal friction and solvent quality on the contact formation dynamics based on non-Markovian diffusion equation supplemented with an exponential sink term accounting for the electron transfer quenching. The mean contact formation time has been derived under Wilemski-Fixman approximation. We show that internal friction induces fractional viscosity dependence of looping time, which will be affected remarkably by solvent quality condition. Besides, internal friction promotes a diffusion-limited mechanism by slowing chain relaxation, while solvent quality being another key factor shifts the critical internal friction for the crossover of the transition from reaction to diffusion-limited regimes. (C) 2018 Elsevier B.V. All rights reserved.