Journal of Polymer Science Part A: Polymer Chemistry, Vol.34, No.4, 567-573, 1996
Polymerization in a Magnetic-Field .10. Solvent Effect in Poly(Methyl Methacrylate) Synthesis
The effect of a continuous external magnetic field on the free radical polymerization of methyl methacrylate was studied with respect to some properties of the solvents used in the reaction. The studies were performed through dilatometric technique in and out a magnetic field of 0.25 T. Ten different solvents were used to underline the dependence between the magnetic field presence, the reaction medium, and the development of the polymerization process. The intervened magnetokinetic effects are attributed to the changes in the multiplicity of the radical pairs owing to the magnetic field influence. There is an interdependence among the viscosity and molar polarization of the solvents and the magnetic field effect.
Keywords:PHOTOINDUCED EMULSION POLYMERIZATION;PHOTO-DECOMPOSITION REACTION;RADICAL ION-PAIRS;METHYL-METHACRYLATE;DIBENZOYL PEROXIDE