A simple hydrothermal route is designed to decorate NiCo2S4 nanoparticles on the surface of N-doped carbon nanotubes to form a coaxial composite (NiCo2S4@NCNT). Inherited the high electrical conductivity from the NCNT and high capacitive performance of NiCo2S4, the optimized NiCo2S4@NCNT composite could significantly reduce the contact resistance and effectively increase the transfer rate of ion and electron and thus benefit for its electrochemical performance enhancement. When employed as a battery-type supercapacitor electrode, the NiCo2S4@NCNT composite exhibits a high capacitance up to 783.5 C g(-1) at 1 A g(-1) and as well as rate performance (74.6% retention with the current density increases from 1 to 50 A g(-1)). Coupled with activated carbon (AC) negative electrode, the as-assembled hydride supercapacitor delivers a maximum energy density of 49.75 Wh kg(-1) at a power density of 774.65Wkg(-1), as well as 88.9% capacitance retained after 3000 cycles at a current density of 10 A g(-1). These above results demonstrate the enormous potential of NiCo2S4@ NCNT in the development of hybrid supercapacitors. (C) 2018 Published by Elsevier B.V.