This article focuses on the development of phase transformation and morphology of low-grade pyrolusite during carbothermal reduction using microwave heating. The XRD, SEM and EDS results show that selective carbothermal reduction of MnxOy and FexOy in pyrolusite is easy to realize with microwave heating, which can reduce MnO2 to MnO, and Fe2O3 to Fe3O4 , rather than FeO. It was also observed that the phases of Mn2O3 , Mn3O4 and MnO appear at 300 degrees C, 450 degrees C and 500 degrees C, respectively. The MnO phase, formed by the accumulation of MnO sphere particle with a diameter of 266.75-420.05 nm, is loose and porous. At a temperature of 750 degrees C, the Mn2SiO4 layer of about 316 nm in thickness, tightly wrapping SiO2 particle is generated at the interface between MnO and SiO2 embedded with MnO. Above 650 degrees C, Fe2O3 in pyrolusite can be transformed into a very dense Fe3O4 phase. (C) 2018 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.