Journal of Industrial and Engineering Chemistry, Vol.64, 461-466, August, 2018
Au ion-mediated self-assembled tyrosine-rich peptide nanostructure embedded with gold nanoparticle satellites
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We report a gold ion-mediated self-assembled tyrosine-rich peptide (TRP) spherical nanostructure with gold nanoparticle (AuNP) satellites (YC7@Ausat). We clarified that non-reduced gold ions, coordinated with TPRs are not only one another critical driving force for TRP spherical self-assembly together with instant thermal transition, but also play a key role to determine the spherical shape of TRP nanostructures. Furthermore, the pH and the concentrations (buffer, peptides, and AuCl4 -) are considered as important parameters to obtain optimal YC7@Ausat nanostructures. In addition, plasmonic properties of YC7@Ausat nanostructures were investigated for localized surface plasmon resonance (LSPR) and surface enhanced Raman scattering (SERS) applications.
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