화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.64, 402-419, August, 2018
DOI10.1016/j.jiec.2018.04.003  Export Citation
The epoxy coating interfacial adhesion and corrosion protection properties enhancement through deposition of cerium oxide nanofilm modified by graphene oxide
Nafise Parhizkar, Bahram Ramezanzadeh1, †, and Taghi Shahrabi†
  • Department of Materials Engineering, Faculty of Engineering, Tarbiat Modares University, P.O. Box: 14115-143, Tehran, Iran
  • 1Department of Surface Coatings and Corrosion, Institute for Color Science and Technology (ICST), P.O. 16765-654, Tehran, Iran
E-mail:,
This paper aims at improving the cathodic disbonding, corrosion protection and adhesion properties of epoxy coating through steel substrate treatment by cerium nanofilm. For this purpose, the cerium film was modified by graphene oxide nanosheets, which are covalently functionalized with silane coupling agent. The performance of this coating was studied by electrochemical impedance spectroscopy, Pull-off adhesion and cathodic delamination tests and the morphology of the modified cerium film was investigated by field-emission scanning electron microscopy. Results revealed that modifying the cerium nanofilm led to the better adhesion strength, corrosion protection performance and lower cathodic delamination rate of epoxy coating.
Keywords:Graphene oxide;Cerium nanofilm;Adhesion;Corrosion;Cathodic disponding
  1. Pour-Ali S, Dehghanian C, Kosari A, Corrosion Sci., 90, 239 (2015)
  2. Saravanan G, Mohan S, Corrosion Sci., 51, 197 (2009)
  3. Chen C, Dong S, Hou R, Hu J, Jiang P, Ye C, Du R, Lin C, Surf. Coat. Technol., 326, 183 (2017)
  4. Wang Z, Han E, Liu F, Qian Z, Zhu L, J. Mater. Sci. Technol., 30, 1036 (2014)
  5. Chen L, Chai S, Liu K, Ning N, Gao J, Liu Q, Chen F, Fu Q, ACS Appl. Mater. Interfaces, 4, 4398 (2012)
  6. Ghanbari A, Attar M, Surf. Coat. Technol., 246, 26 (2014)
  7. Maksimovic M, Miskovic-Stankovic V, Corrosion Sci., 33, 271 (1992)
  8. Bi H, Sykes J, Prog. Org. Coat., 87, 83 (2015)
  9. Alam MA, Sherif ESM, Al-Zahrani SM, Int. J. Electrochem. Sci., 8, 3121 (2013)
  10. Koehler E, Corrosion, 40, 5 (1984)
  11. Sababi M, Terryn H, Mol JMC, Prog. Org. Coat., 105, 29 (2017)
  12. Zhu W, Li WF, Mu SL, Yang YY, Zuo X, Appl. Surf. Sci., 384, 333 (2016)
  13. Zhang H, Yao G, Wang S, Liu Y, Luo H, Surf. Coat. Technol., 202, 1825 (2008)
  14. Zhao M, Wu S, Luo J, Fukuda Y, Nakae H, Surf. Coat. Technol., 200, 5407 (2006)
  15. Zimmermann D, Munoz AG, Schultze JW, Electrochim. Acta, 48(20-22), 3267 (2003)
  16. Zarei A, Afshar A, Mater. Process. Prop., 28, 615 (2009)
  17. Asadi N, Naderi R, Saremi M, Arman S, Fedel M, Deflorian F, J. Sol Gel Sci. Technol., 70, 329 (2014)
  18. Figueira R, Silva CJ, Pereira E, J. Coat. Technol. Res., 12, 1 (2015)
  19. Du YJ, Damron M, Tang G, Zheng H, Chu CJ, Osborne JH, Prog. Org. Coat., 41, 226 (2001)
  20. Rezaee N, Attar M, Ramezanzadeh B, Surf. Coat. Technol., 236, 361 (2013)
  21. Sharma A, Sharma AK, Metal Finish., 1989, 87 (1989)
  22. Zhang X, Van den Bos C, Sloof W, Hovestad A, Terryn H, De Wit J, Surf. Coat. Technol., 199, 92 (2005)
  23. Zhang X, Sloof W, Hovestad A, Van Westing E, Terryn H, De Wit J, Surf. Coat. Technol., 197, 168 (2005)
  24. Mahdavian M, Ramezanzadeh B, Akbarian M, Ramezanzadeh M, Kardar P, Alibakhshi E, Farashi S, J. Ind. Eng. Chem., 55, 244 (2017)
  25. Otitoju TA, Ahmad AL, Ooi BS, J. Ind. Eng. Chem., 47, 19 (2017)
  26. Sanchez-Amaya J, Blanco G, Garcia-Garcia F, Bethencourt M, Botana F, Surf. Coat. Technol., 213, 105 (2012)
  27. Wang C, Jiang F, Wang F, Corrosion Sci., 46, 75 (2004)
  28. Hosseini M, Ashassi-Sorkhabi H, Ghiasvand HAY, J. Rare Earths, 25, 537 (2007)
  29. Majdi MR, Danaee I, Afghahi SSS, Mater Res., 20(2), 445 (2017)
  30. Onofre-Bustamante E, Dominguez-Crespo MA, Torres-Huerta AM, Olvera-Martinez A, Genesca-Llongueras J, Rodriguez-Gomez FJ, J. Solid State Electrochem., 13, 1785 (2009)
  31. Kobayashi Y, Fujiwara Y, Electrochim. Acta, 51(20), 4236 (2006)
  32. Ramezanzadeh B, Vakili H, Amini R, J. Ind. Eng. Chem., 30, 225 (2015)
  33. Vakili H, Ramezanzadeh B, Amini R, Corrosion Sci., 94, 466 (2015)
  34. Mahidashti Z, Shahrabi T, Ramezanzadeh B, Appl. Surf. Sci., 390, 623 (2016)
  35. Ramezanzadeh B, Rostami M, Appl. Surf. Sci., 392, 1004 (2017)
  36. Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M, Corrosion Sci., 118, 69 (2017)
  37. Xu H, Yan B, Zhang K, Wang J, Li S, Wang C, Shiraishi Y, Du Y, Yang P, Electrochim. Acta, 245, 227 (2017)
  38. Xu H, Zhang K, Yan B, Wang J, Wang CQ, Li SM, Gu ZL, Du YK, Yang P, J. Power Sources, 356, 27 (2017)
  39. Xu H, Yan B, Li SM, Wang J, Wang CQ, Guo J, Du YK, Chem. Eng. J., 334, 2638 (2018)
  40. Xu H, Yan B, Li S, Wang J, Wang C, Guo J, Du Y, ACS Sustain.Chem. Eng., 6(1), 609 (2018)
  41. Haeri SZ, Ramezanzadeh B, Asghari M, J. Colloid Interface Sci., 493, 111 (2017)
  42. Miraftab R, Karimi B, Bahlakeh G, Ramezanzadeh B, J. Ind. Eng. Chem., 53, 348 (2017)
  43. Hayatgheib Y, Ramezanzadeh B, Kardar P, Mahdavian M, Corrosion Sci., 133, 358 (2018)
  44. Nikpour B, Ramezanzadeh B, Bahlakehb G, Mahdavian M, Corrosion Sci., 127, 240 (2017)
  45. Parhizkar N, Shahrabi T, Ramezanzadeh B, Corrosion Sci., 123, 55 (2017)
  46. Lee CY, Bae JH, Kim TY, Chang SH, Kim SY, Compos. Pt. A-Appl. Sci. Manuf., 75, 11 (2015)
  47. Layek RK, Nandi AK, Polymer, 54(19), 5087 (2013)
  48. Wang S, Chia PJ, Chua LL, Zhao LH, Png RQ, Sivaramakrishnan S, Zhou M, Goh RGS, Friend RH, Wee ATS, Ho PKH, Adv. Mater., 20(18), 3440 (2008)
  49. Stankovich S, Piner RD, Nguyen ST, Ruoff RS, Carbon, 44, 3342 (2006)
  50. Ramezanzadeh B, Ghasemi E, Mandavian M, Changizi E, Moghadam MHM, Chem. Eng. J., 281, 869 (2015)
  51. Ramezanzadeh B, Niroumandrad S, Ahmadi A, Mahdavian M, Moghadam MHM, Corrosion Sci., 103, 283 (2016)
  52. Tong LB, Zhang JB, Xu C, Wang X, Song SY, Jiang ZH, Kamado S, R. Cheng L, Zhang HJ, Carbon, 109, 340 (2016)
  53. Chen J, Yao B, Li C, Shi G, Carbon, 64, 225 (2013)
  54. Luo D, Zhang G, Liu J, Sun X, J. Phys. Chem. C, 115, 11327 (2011)
  55. Saxena S, Tyson TA, Shukla S, Negusse E, Chen H, Bai J, Appl. Phys. Lett., 99, 013104 (2011)
  56. Li D, Neumann A, J. Colloid Interface Sci., 137, 304 (1990)
  57. Ramezanzadeh B, Ghasemi E, Mahdavian M, Changizi E, Moghadam MM, Carbon, 93, 555 (2015)