Journal of Industrial and Engineering Chemistry, Vol.64, 188-193, August, 2018
Surface plasmon resonance-enhanced solar-driven photocatalytic performance from Ag nanoparticles-decorated Ti3+ self-doped porous black TiO2 pillars
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The tiny Ag nanoparticles-uniformly decorated Ti3+ self-doped porous black TiO2 pillars (Ag-TPBTPs) are prepared, which show obvious surface plasmon resonance (SPR) and extend the photoresponse to visible light and near-infrared region (~1500 nm). The Ag-TPBTPs exhibit excellent solar driven photocatalytic activities by mineralizing of high-toxic 2,4-dichlorophenol (~99%), which is three times higher than that of the pristine TiO2. The remarkable solar-driven photocatalytic performance can be ascribed to the porous pillars structure offering more surface active sites, the self-doped Ti3+ and SPR effect of Ag nanoparticles improving the utilization of solar light, and enhancing the spatial separation efficiency of photogenerated charge carriers.
Keywords:Black TiO2;Ti3+ self-doping;Ag nanoparticle;Surface plasmon resonance;Solar-driven photocatalysis
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