화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.64, 134-142, August, 2018
DOI10.1016/j.jiec.2018.03.009  Export Citation
Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes
Parthiban Pazhamalai1, Karthikeyan Krishnamoorthy1, Vimal Kumar Mariappan1, and Sang-Jae Kim1, 2, †
  • 1Department of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of Korea
  • 2Department of Advanced Convergence Science and Technology, Jeju National University, Jeju 63243, Republic of Korea
E-mail:
Herein, we demonstrated a facile sonochemical preparation of manganese hexacyanoferrate (Mn-HCF) and examined its use as an intercalative-type electrode for Li-ion hybrid capacitors (LHCs). The X-ray diffraction, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopic analyses revealed the formation of Mn-HCF nanocubes. The electrochemical analyses revealed the presence of ion-intercalation pseudocapacitance in the Mn-HCF electrode with a specific capacity of 81.59 mAh g-1. In the view of practical applications, we designed a Mn-HCFkgraphene LHC which delivered a high specific capacitance (79.52 F g-1) and energy density (44.18 Wh kg-1), respectively. Overall, our results highlight the significance of Mn-HCF towards cost-effective energy storage devices.
Keywords:Li-ion hybrid capacitor;Manganese hexacyanoferrate;Graphene;Aqueous electrolyte;Energy density
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