화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.7, 1433-1440, July, 2018
DOI10.1007/s11814-018-0050-8  Export Citation
Comparative study of CHA- and AEI-type zeolytic catalysts for the conversion of chloromethane into light olefins
Yong Hun Shin, Sungjoon Kweon1, Min Bum Park1, †, and Ho-Jeong Chae†
  • CO2 Energy Vector Research Group, Carbon Resources Institute, Korea Research Institute of Chemical Technology, Daejeon 34114, Korea
  • 1Innovation Center for Chemical Engineering, Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, Korea
E-mail:,
Three pairs of CHA- and AEI-type zeolytic materials with similar crystallite size but with different framework atoms, i.e., silicoaluminophosphate SAPO-34 and SAPO-18, aluminosilicate SSZ-13 and SSZ-39, and titaniumincorporated TiAPSO-34 and TiAPO-18, were prepared and their catalytic activities of chloromethane into light olefins were compared according to the structure types, as well as acidic properties. The AEI-type catalysts were found to have lower ethene/propene ratios, indicating relatively higher propene selectivity, because their aei-cage was larger compared to the cha-cage. However, all the CHA-type catalysts exhibited better activity and higher selectivity to light olefins. Both H-SAPO-34 and H-TiAPSO-34 showed good catalytic stability over all the reaction times studied here. When compared to H-SAPO-34, however, H-TiAPSO-34 exhibited ca. 20mol% higher selectivity to ethene and propene, despite a similar total density of acid site. This performance may be due to the higher strength of medium acid sites.
Keywords:AEI;CHA;Chloromethane Conversion;Light Olefins;TiAPSO-34
  1. Horn R, Schlogl R, Catal. Lett., 145(1), 23 (2015)
  2. Tang P, Zhu Q, Wu Z, Ma D, Energy Environ. Sci., 7, 2580 (2014)
  3. Wei Y, Zhang D, Liu Z, Su BL, Chin, J. Catal., 33, 11 (2012)
  4. Tian P, Wei Y, Ye M, Liu Z, ACS Catal., 15, 1922 (2015)
  5. Olsbye U, Saure OV, Muddada NB, Bordiga S, Lamberti C, Nilsen MH, Lillerud KP, Svelle S, Catal. Today, 171(1), 211 (2011)
  6. Svelle S, Aravinthan S, Bjorgen M, Lillerud KP, Kolboe S, Dahl IM, Olsbye U, J. Catal., 241(2), 243 (2006)
  7. Wei Y, Zhang D, Chang F, Xia Q, Su BL, Liu Z, Chem. Commun., 5999 (2009).
  8. Fickel DW, Sabnis KD, Li LY, Kulkarni N, Winter LR, Yan BH, Chen JGG, Appl. Catal. A: Gen., 527, 146 (2016)
  9. Sun Y, Campbell SM, Lunsford JH, Lewis GE, Palke D, Tau LM, J. Catal., 143, 32 (1993)
  10. Xu T, Zhang QH, Song H, Wang Y, J. Catal., 295, 232 (2012)
  11. Ibanez M, Gamero M, Ruiz-Martinez J, Weckhuysen BM, Aguayo AT, Bilbao J, Castano P, Catal. Sci. Technol., 6, 296 (2016)
  12. Li N, Zhang YY, Chen L, Au CT, Yin SF, Microporous Mesoporous Mater., 227, 76 (2016)
  13. Wei YX, Zhang DZ, Xu L, Liu ZM, Su BL, Catal. Today, 106(1-4), 84 (2005)
  14. Wei YX, Zhang DZ, Liu ZM, Su BL, J. Catal., 238(1), 46 (2006)
  15. Wei Y, He Y, Zhang D, Xu L, Meng S, Liu Z, Su BL, Microporous Mesoporous Mater., 90, 188 (2006)
  16. Wei YX, Zhang DZ, He YL, Xu L, Yang Y, Su BL, Liu ZM, Catal. Lett., 114(1-2), 30 (2007)
  17. Wei YX, Zhang DZ, Xu L, Chang FX, He YL, Meng SH, Su BL, Liu ZM, Catal. Today, 131(1-4), 262 (2008)
  18. Nilsen MH, Svelle S, Aravinthan S, Olsbye U, Appl. Catal. A: Gen., 367(1-2), 23 (2009)
  19. Zhang A, Sun S, Komon ZJA, Osterwalder N, Gadewar S, Stoimenov P, Auerbach DJ, Stucky GD, McFarland EW, Phys. Chem. Chem. Phys., 13, 2550 (2011)
  20. Jiang Z, Shen BX, Zhao JG, Wang L, Kong LT, Xiao WG, Ind. Eng. Chem. Res., 54(49), 12293 (2015)
  21. Juamain D, Su BL, Catal. Today, 73(1-2), 187 (2002)
  22. Zhang DH, Wei YX, Xu L, Du AP, Chang FX, Su BL, Liu ZM, Catal. Lett., 109(1-2), 97 (2006)
  23. Xu T, Song H, Deng W, Zhang Q, Wang Y, Chin. J. Catal., 34, 2047 (2013)
  24. Kong LT, Shen BX, Zhao JG, Liu JC, Ind. Eng. Chem. Res., 53(42), 16324 (2014)
  25. Gamero M, Aguayo AT, Ateka A, Perez-Uriarte P, Gayubo AG, Bilbao J, Ind. Eng. Chem. Res., 54(32), 7822 (2015)
  26. Dusselier M, Deimund MA, Schmidt JE, Davis ME, ACS Catal., 5, 6078 (2015)
  27. Deimund MA, Harrison L, Lunn JD, Liu Y, Malek A, Shayib R, Davis ME, ACS Catal., 6, 542 (2016)
  28. Wang Y, Chen SL, Jiang YJ, Cao YQ, Chen F, Chang WK, Gao YL, RSC Adv., 6, 104985 (2016)
  29. Martinez-Franco R, Li Z, Martinez-Triguero J, Moliner M, Corma A, Catal. Sci. Technol., 6, 2796 (2016)
  30. Martin N, Li Z, Martinez-Triguero J, Yu J, Moliner M, Corma A, Chem. Commun., 52, 6072 (2016)
  31. International Zeolite Association, Structure Commission, http://www.iza-structure.org.
  32. Xu L, Liu Z, Du A, Wei Y, Sun Z, Stud. Surf. Sci. Catal., 147, 445 (2004)
  33. Aghaei E, Haghighi M, Pazhohniya Z, Aghamohannadi S, Microporous Mesoporous Mater., 226, 331 (2016)
  34. Chae HJ, Park SS, Shin YH, Park MB, Microporous Mesoporous Mater., 259, 60 (2018)
  35. Itakura M, Goto I, Takahashi A, Fujitani T, Ide Y, Sadakane M, Sano T, Microporous Mesoporous Mater., 144, 91 (2011)
  36. Chen JS, Wright PA, Thomas JM, Natarajan S, Marchese L, Bradley SM, Sankar G, Catlow CR, Gaiboyes PL, Townsend RP, Lok CM, J. Phys. Chem., 98(40), 10216 (1994)
  37. Wagner P, Nakagawa Y, Lee GS, Davis ME, Elomari S, Medrud RC, Zones SI, J. Am. Chem. Soc., 122(2), 263 (2000)
  38. Treacy MMJ, Higgins JB, Collection of Simulated XRD Powder Patterns for Zeolites, 5th Ed., Elsevier, Amsterdam (2007).
  39. Park MB, Vicente A, Fernandez C, Hong SB, Phys. Chem. Chem. Phys., 15, 7604 (2013)
  40. Lee KY, Chae HJ, Jeong SY, Seo G, Appl. Catal. A: Gen., 369(1-2), 60 (2009)
  41. Man PP, Briend M, Peltre MJ, Lamy A, Beaunier P, Barthomeuf D, ZKG Int., 11, 563 (1991)