화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.26, No.6, 552-556, June, 2018
DOI10.1007/s13233-018-6066-4  Export Citation
Synthesis of Conjugated Materials Based on Benzodithiophene - Benzothiadazole and Their Application of Organic Solar Cells
Nadhila Sylvianti, Youn Hwan Kim, Dong Geun Kim, Ratna Dewi Maduwu, Ho Cheol Jin, Doo Kyung Moon1, and Joo Hyun Kim†
  • Department of Polymer Engineering, Pukyong National University, Busan 48547, Korea
  • 1Department of Materials Chemistry and Engineering, Konkuk Univerisity, Seoul 05029, Korea
E-mail:
Electron acceptor-donor-acceptor type oligomers based on benzothiadiazole (BT) unit and a (4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl) bis(trimethylstannane) (BDT) unit have been designed and prepared as electron-donating materials, which are 2,6-[5-(7-methyl-benzo[1,2,5]thiadiazol-4-yl)-thiophen-2-yl]-4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene) (BDT-TBT) and 2,6-[5′-(3′-hexyl-[2,2′]bithiophenyl-5-yl)-7-methyl-benzo[1,2,5]thiadiazole]-4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene) (BDT-THTBT), for Organic Solar Cells (OSCs) with PC71BM as electron-accepting materials. The HOMO energy level is elevated by the number of thiophene ring as a p-bridge, which lowers the band gap. Inverted-type organic solar cells (OSCs) with a configuration of ITO/ZnO/BDT-TBT (or BDT-THTBT):PC71BM/MoO3/Al are fabricated. OSC based on BDT-THTBT exhibits the highest power conversion efficiency (PCE) of 1.04% with the best J sc of 4.20 mA/cm2.
Keywords:conjugated oligomer;benzodithiophene;benzothiadiazole;thiophene;organic solar cell
  1. Oh S, Badgujar S, Kim DH, Lee WE, Khan N, Jahandar M, Rasool S, Song CE, Lee HK, Shin WS, Lee JC, Moon SJ, Lee SK, J. Mater. Chem. A, 5, 15923 (2017)
  2. Yi YQ, Feng H, Chang M, Zhang H, Wan X, Li C, Chen Y, J. Mater. Chem. A, 5, 17204 (2017)
  3. Somasundaram S, Jeon S, Park S, Macromol. Res., 24(3), 226 (2016)
  4. Ha YH, Lee JE, Hwang MC, Kim YJ, Lee JH, Park CE, Kim YH, Macromol. Res., 24(5), 457 (2016)
  5. Kim HY, Choi MH, Han YW, Moon DK, Haw JR, J. Ind. Eng. Chem., 33, 209 (2016)
  6. Gasparini N, Lucera L, Salvador M, Prosa M, Spyropoulus GD, Kubis P, Egeelhaf HJ, Brabec CJ, Ameri T, Energy Environ. Sci., 10, 885 (2017)
  7. Deng D, Zhang Y, Zhang J, Wang Z, Zhu L, Fang J, Xia B, Wang Z, Lu K, Ma W, Wei Z, Nat. Commun., 7, 13740 (2016)
  8. Liu Y, Chen CC, Hong Z, Gao J, Yang Y, Zhou H, Dou L, Li G, Yang Y, Sci. Rep., 3, 3356 (2013)
  9. Xin R, Feng J, Zeng C, Jiang W, Zhang L, Meng D, Ren Z, Wang Z, Yan S, ACS Appl. Mater. Interfaces, 9, 2739 (2017)
  10. Dominguez R, Montcada NF, Cruz P, Palomares E, Langa F, Phys. Chem. Chem. Phys., 19, 3640 (2017)
  11. Zhang Q, Kan B, Liu F, Long G, Wang X, Chen X, Zuo Y, et al., Nat. Photonics, 9, 35 (2015)
  12. Chen W, Zhang Q, J. Mater. Chem. C, 5, 1275 (2017)
  13. Liang N, Jiang W, Hou J, Wang Z, Mater. Chem. Front., 1, 1291 (2017)
  14. Ku J, Lansac Y, YH, Jang J, Phys. Chem. C, 115, 21508 (2011)
  15. Eom Y, Song CE, Shin WS, Lee SK, Lim E, J. Ind. Eng. Chem., 45, 338 (2017)
  16. Ye L, Jiao XC, Zhang H, Li SS, Yao HF, Ade H, Hou JH, Macromolecules, 48(19), 7156 (2015)
  17. Yao HF, Ye L, Zhang H, Li SS, Zhang SQ, Hou JH, Chem. Rev., 116(12), 7397 (2016)
  18. Pai RK, Ahipa TN, Hemavathi B, RSC Adv., 6, 23760 (2016)
  19. Jeon Y, Kim TM, Kim JJ, Hong JI, New J. Chem., 39, 9591 (2015)
  20. Karakus M, Apaydin DH, Yildiz DE, Toppare L, Cirpan A, Polymer, 53(6), 1198 (2012)
  21. Sylvianti N, Kim YW, Marsya MA, Moon DK, Kim JH, Synth. Met., 221, 127 (2016)
  22. Chen P, Nakano K, Suzuki K, Hashimoto K, Kikitsu T, Hashizume D, Koganezawa T, Tajima K, ACS Appl. Mater. Interfaces, 9, 4758 (2017)
  23. Bundgaard E, Krebs FC, Sol. Energy Mater. Sol. Cells, 91(11), 954 (2007)
  24. Zhang F, Wu D, Xu Y, Feng X, J. Mater. Chem., 21, 17590 (2011)
  25. Elumalai NV, Uddin A, Energy Environ. Sci., 9, 391 (2016)
  26. Jiang X, Yang Y, Zhu J, Lau TK, Cheng P, Lu X, Zhan X, Chen X, J. Mater. Chem. C, 5, 8179 (2017)