화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.62, 156-165, June, 2018
DOI10.1016/j.jiec.2017.12.053  Export Citation
Carbon dioxide hydrogenation to methanol over multi-functional catalyst: Effects of reactants adsorption and metal-oxide(s) interfacial area
Mei Kee Koh, Yee Jie Wong, Siang Piao Chai1, and Abdul Rahman Mohamed†
  • Low Carbon Economy (LCE) Research Group, School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
  • 1Multidisciplinary Platform of Advanced Engineering, Chemical Engineering Discipline, School of Engineering, Monash University, Jalan Lagoon Selatan, 47500 Bandar Sunway, Selangor, Malaysia
E-mail:
Copper-based catalysts with different metal-oxide(s) composition were synthesized and applied in CO2 hydrogenation to methanol. The metal component(s) (Cu, Zn and/or Mn) were dispersed on high surface area SBA-15. Correlations between the adsorption properties of catalysts and the catalytic performances reveal that a catalyst with both strong hydrogenation strength and moderate CO2 adsorption strength is crucial for achieving high CO2 conversion. Additionally, the availability of metal-oxide(s) interfacial area greatly enhances methanol selectivity. An adequate balance between H2 and CO2 adsorptions as well as metal-oxide(s) interfacial area were responsible for the high catalytic activity achieved in this study.
Keywords:CO2 hydrogenation;Methanol;Copper-based multi-component catalyst;Adsorption properties;Metal-oxide(s) interfaces
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