In the last decades, increasing industrial development has led to huge consumption of plastic materials, due to their versatility and low cost. Therefore, the implementation of efficient and environmentally friendly recycling technologies is of great importance. This study proposes an alternative separation process for recycling mixtures of plastic wastes, using a tribo-electrostatic separation process. The methodology adopted in this work was firstly characterization of the polymeric wastes, followed by preparation of the wastes using different unit operation processes (washing, drying, and comminution), tribo-charging, and electrostatic separation of different combinations of plastics (HDPE/PP, LDPE/PP, and PET/PVC). Various parameters were evaluated in the tribo-charging process and the electrostatic deflection. Separation of a mixture of HDPE and PP achieved PP recovery of 92.8% (purity of 95.7%) and HDPE recovery of 95.9% (purity of 93.1%). Recovery and purity values higher than 90.2% and 95.9% were obtained for PP/LDPE and PET/PVC mixtures, respectively. These results demonstrated that tribo-electrostatic separation is a promising and efficient method for use in the recycling of plastic wastes. The process studied enabled significant recoveries of the components at high levels of purity. (C) 2018 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.