Polymer, Vol.142, 285-292, 2018
Predictive durability of polyethylene terephthalate toward hydrolysis over large temperature and relative humidity ranges
The hydrolytic stability of poly(ethylene terephthalate) (PET) has already been largely reported. The chemical reactions induced by damp-heat exposure are well-known, and various kinetic expressions for the degradation have been presented. Using the data from previous studies, a new model for degradation is proposed. This model combines the effect of temperature and humidity in a single equation. Three parameters are utilized: the classical pair of activation energy (Ea) and pre-exponential factor (f(0)), and the reaction order (n) to the relative humidity (RH). The model may be used to fit the degradation data from various sources describing the hydrolysis over a large range of conditions (40-100 % RH, 60-160 degrees C). In addition a prediction of the crystallinity changes brought about by hydrolytic chain scission was performed. Prediction of useful lifetime in moist heat is also possible (hydrolysis of 0.2% ester moieties in the polymer). (C) 2018 Elsevier Ltd. All rights reserved.