화학공학소재연구정보센터
Petroleum Chemistry, Vol.58, No.2, 145-151, 2018
Ultrafiltration of Oil-in-Water Emulsions with a Dynamic Nylon-Polystyrene Membrane
Dynamic nylon-polystyrene membranes with polystyrene contents of 2.6 and 4.1 wt % have been obtained by applying polystyrene with a particle size of 142-452 nm onto the surface of a nylon membrane with a pore size of 0.45 mu m. The deposition of polystyrene onto the surface of the nylon membrane was indirectly confirmed by Fourier-transform IR spectroscopy and probe microscopy. The contact angle of distilled water on the membrane has been found to increase from 44.5A degrees to 106.2A degrees as a result of the deposition of polystyrene particles onto the surface of the initial membrane. The specific productivity of the initial and modified membranes with respect to distilled water and a water-oil emulsion was determined. It has been found that the membrane modification leads to an increase in the degree of removal of petroleum products from an oil-in-water emulsion by 62%; the size of particles separated by the membrane after modification decreased from 450 to 151 nm. It has also been revealed that the specific productivity of the nylon-polystyrene membrane and the original nylon membrane is restored to 98 and 90% of the initial values, respectively, by regeneration.