A novel conductive membrane with Fe/Mn/C/F/O elements is developed, it functions as the catalytic cathode of MFC and the antifouling filter of MBR simultaneously, in a newly designed integrated wastewater treatment system, without proton exchange membrane (PEM). The optimal conductive membrane is characterized using SEM-EDX, XRD and XPS. BET and porous structure analysis of the grounded membrane material indicate a narrow and small pore size (2-7 nm). The membrane surface is rich in Fe species (Fe - Fe2O3 - Fe3O4) and manganese oxide (MnO2). Its characteristics such as excellent electro-chemical oxygen reduction reaction (ORR) activity, high clear water flux (> 240 L/(m(2).h)) and better antifouling filtration performance are further confirmed. The new system features bio-electrochemical system (BES) and integrates bio-filtration (trickling filter and air contact oxidation bed) and proton transfer through quartz sand chamber (QSC) which eliminates the use of expensive proton exchange membrane. The system removes chemical oxygen demand (> 97.4%), ammonia nitrogen (> 96.7%), total phosphorus (> 98.0%) effectively, and it simultaneously generates electricity (446 mW/m(3)). The low cost and high performances, economic and advantageous system has good compatibility with existing wastewater treatment facilities and a wide application prospect.