We first report a composite of molybdenum disulfide (MoS2) nanoflake arrays (MNFs) and tungsten trioxide (WO3) nanorod arrays (WNRs) directly grown on a copper (Cu) substrate. This composite is characterized in detail by scanning and transmission electron microscopes (SEM/TEM), X-ray diffraction (XRD), Raman and X-ray photoelectron spectroscopy (XPS). All of the evidences indicate that the obtained composite is a heterojunction. The supercapacitive properties of MNFs-WNRs composite heterojunction are measured systematically by using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) techniques. The heterojunction exhibits a high specific capacitance of 522 F g(-1) at 0.5 A g(-1), a high capacitance retention (95%) after 5000 cycles and a low charge transfer resistance (1.0 Omega). And this kind of heterojunction has advantages of both MoS2 and WO3, which can be a better candidate for supercapacitive electrode material. (c) 2018 Elsevier Ltd. All rights reserved.