The corrosion behavior of electrodeposited binary Fe-Mo and ternary Fe-Mo-P coatings on mild steel substrates as cathodes was investigated in the simulated electrolyte for chlorate production, containing 300 g L-1 of NaCl and 4 g L-1 of K2Cr2O7 at 80 degrees C. Electrochemical noise measurements (ENM), linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and scanning reference electrode technique (SRET) were used in this investigation under open circuit potential (OCP) in the simulated shutdown conditions of the chlorate production industry (decay). A filiform corrosion was observed on the surface of all electrodes and in the case of mild steel, a number of pitting sites were also detected. The ternary cathode (Fe54Mo30P16) containing the highest phosphorous content showed the best resistance to corrosion compared to other coatings and mild steel. Using the ENM technique, a decrease of 67% of the corrosion rate was measured for the Fe54Mo30P16 coating compared to Fe53Mo47 after 72 h of decay, whereas mild steel showed 6 times more corrosion compared to the Fe54Mo30P16 electrode. The addition of phosphorous to the Fe53Mo47 alloy promoted resistance to corrosion. The corrosion resistance of ternary alloys of Fe-Mo-P were improved with the increase of phosphorous content from 9 to 16 at.%. According to LPR and EIS measurements, the Fe54Mo30P16 showed 56%-60% less corrosion compared to the binary Fe53Mo47 electrode. Crown Copyright (C) 2018 Published by Elsevier Ltd. All rights reserved.