Chemical Physics Letters, Vol.699, 32-39, 2018
Co-sensitization of ruthenium(II) dye-sensitized solar cells by coumarin based dyes
Co-sensitization technique has been appraised for attaining enhanced performance in dye-sensitized solar cells (DSSCs). DSSCs are fabricated with a heteroleptic Ru(II) sensitizer (RDAB1) containing 4,4'-dia mino-2,2'-bipyridine (dabpy) ligand, co-sensitized with electron donor-acceptor type coumarin containing thiophene (CT) and indole (CI) moieties. The individual overall power conversion efficiency of the sensitizer is 5.44%. Enhanced power conversion efficiencies of 6.34% and 7.09% were observed when RDAB1 was co-sensitized with Coumarin containing CI and CT respectively. The enhanced PCE can be attributed to the presence of co-sensitizers which effectively overcome the light absorption by I-/I-3(-), dye aggregation and charge recombination. (C) 2018 Elsevier B.V. All rights reserved.
Keywords:Diamino bipyridine (dabpy);Coumarin;Co-sensitizer;Dye-sensitized solar cells;Ruthenium complex