Functional surfaces that enable both hot water repellency and effective condensation have attracted great interest in both academic research and practical applications. Two kinds of 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids (ILs) with different chain lengths ([C(n)mIm][PF6], n = 4 ([BmIm][PF6]), n = 8 ([OmIm][PF6])) are respectively infused into the porous surface constructed by nanocone arrays of (Ni, Co)-(CO3)(0.5)(OH)(0.11)H2O (NiCo-NCA), aiming to produce slippery surfaces (SSs) with stable non-wetting performance. Before the ILs infusion, the NiCo-NCA surface is functionalized by low surface energy material for conferring superhydrophobicity. The superhydrophobicity of the modified NiCo-NCA becomes ineffective after the heat treatment up to about 240 degrees C due to the formation of cracks on the surface. However, the slippery surfaces can be maintained in the ILs-infused samples followed by the same heat treatment due to the self-healing ability and thermal stability of the infused fluids. Moreover, hot water droplets are repellent on the ILs-infused SSs while pinned on the superhydrophobic surface. The nucleation process of condensing water droplets is easier on the ILs-infused SSs than that on the superhydrophobic surface. The sliding speed of the condensed water and the hot water droplets on the [OmIm][PF6]-infused SS are slower than those on the [BmIm][PF6]-infused SS due to the higher viscosity of [OmIm][PF6]. As well, the ILs-infused SSs can endure physical damage and impacting droplet. The ILs-infused SSs shows promise potential applications in hot liquid self-cleaning and high efficiency droplet manipulation.