Spinel Li4Ti5O12 (LTO) holds great potential used as lithium ion battery(LIB) anode material for various hybrid, plug-in, and pure electrical vehicle applications. However, the low intrinsic conductivity and much underused capacity pose serious obstacles in practice for its wider and deeper utilization. Here we demonstrate a facile approach by which an LTO/Si/cyclized-polyacrylonitrile (PAN) inorganic/polymer composite is designed and implemented in attempt to tackle both challenges. Our results show that an optimal Si amount is needed in the composite so as to fully promote underused LTO capacity in a stable state while cyclized PAN not only improves conductivity, reaction kinetics and charge transfer resistance of the electrode through its turbostratic transition, but to much extent acts as a resilient binder to offset volumetric expansion caused by Si. The optimized composite exhibits admirable capacity and cycling performance during long-term operation. (C) 2017 Elsevier B.V. All rights reserved.