Applied Surface Science, Vol.435, 1072-1079, 2018
Non-woven PET fabric reinforced and enhanced the performance of ultrafiltration membranes composed of PVDF blended with PVDF-g-PEGMA for industrial applications
Ultrafiltration (UF) membranes composed of poly(vinylidene fluoride) (PVDF) blended with poly(vinylidene fluoride)-graft-poly(ethylene glycol) methyl ether methacrylate (PVDF-g-PEGMA) can present high flux and excellent foulant removal efficiencies under suitable preparation conditions. However, these PVDF/PVDF-g-PEGMA blended membranes cannot be applied industrially because of the insufficient mechanical strength (strength-to-break value of 8.4 +/- 0.6 MPa). We incorporated two types of non-woven polyethylene terephthalate (PET) fabrics (thin hydrophobic and thick hydrophilic fabrics) as support layers to improve the mechanical properties of the blended membranes. The thin and thick PET fabrics were able to significantly improve the tensile strength to 23.3 +/- 3.7 MPa and 30.1 +/- 1.4 MPa, respectively. The PET fabrics had a limited impact on the separation-related membrane performance such as hydrophilicity, foulant rejection, whereas the mechanical strength and pure water flux was improved several folds. The enhanced flux was attributed to the higher surface porosity and wider finger-like voids in the cross-section. The thin PET fabric with larger porosity was able to maintain a consistent toughness simultaneously; thus it is recommended as a support material for this blended membrane. (c) 2017 Elsevier B.V. All rights reserved.
Keywords:Poly(vinylidene fluoride) (PVDF);Ultrafiltration membrane;Amphiphilic copolymer;Polyethylene terephthalate (PET) fabric;Support layer