석탄 폐석을 이용한 합성제올라이트 제조 및 흡착성능 분석에 대한 연구

정유식; 이경우; 박지윤; 이영우; You Shick Jung; Kyung Woo Lee; Ji Yun Park; Young Woo Rhee

Clean Technology, Vol.24, No.1, 21-26, March, 2018

DOI10.7464/ksct.2018.24.1.021 Export Citation

석탄 폐석을 이용한 합성제올라이트 제조 및 흡착성능 분석에 대한 연구

Manufacture of Synthesis Zeolite using Coal Waste and Study of Analysis for Adsorption Performance

정유식^†, 이경우, 박지윤¹, 이영우¹

㈜지엔티엔에스, 25440 강원도 강릉시 과학단지로 106-31
¹충남대학교 에너지과학기술대학원, 34134 대전광역시 유성구 대학로 99

You Shick Jung^†, Kyung Woo Lee, Ji Yun Park¹, and Young Woo Rhee¹

GNTNS Co., Ltd., 106-31 Gwahakdanji-ro, Gangneung-si, Gangwon-do 25440, Korea
¹Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yusung-gu, Daejeon 34134, Korea

E-mail:

초록

석탄은 오랜 전부터 사용해온 유용한 산업 자원이다. 그러나 채굴과정에서 많은 폐기물인 석탄 폐석이 발생된다. 석탄 폐석은 주변 환경오염의 주범이며, 그 양 또한 수억 톤이 적치된 상태이다. 이러한 석탄 폐석에 포함된 성분 중 상당량이 SiO2와 Al2O3 성분이고 이것은 여러 산업에서 유용하게 사용되는 제올라이트의 주원료이기도 하다. 본 연구는 석탄 폐석을 이용하여 제올라이트를 합성하고, 상용 제올라이트와의 물성 및 흡착 성능을 비교한 것이다. 합성제올라이트는 상용 제올라이트와 유사한 물성을 보여주고 있으며, 대기 환경오염 유발가스(CO2, Toluene, SO2, 등)에 대한 흡착성능 또한 우수하였다.

The coal is a useful industrial resource for a long time. However, coal waste is generated by the mining process. Coal wastes are the main cause of pollution in the surrounding environment, and the amount of coal waste is set at hundreds of millions of tons. Significant amounts of these components in the coal waste are SiO2 and Al2O3, which is also the main source of zeolites useful in various industries. This study is that the synthesis-zeolite was prepared from coal waste and properties and adsorption performance of synthesis-zeolite were compared with commercial zeolite. The synthesis-zeolite is showed similar properties to the commercial zeolite and also showed excellent adsorption performance against atmospheric pollution induced gases (CO2, Toluene, SO2, etc).

Keywords:Zeolite;Coal waste;Adsorption performance;Gangue;Synthesis zeolite from waste

[References]

http://news.kmib.co.kr/article/view.asp?arcid=0923702824&code=11131413&cp (accessed Nov. 2017).
Belviso C, Cavalcante F. Lettino A, Fiore S, Appl. Clay Sci., 80-81, 162 (2013)
Izidoro JD, Fungaro DA, Abbott JE, Wang SB, Fuel, 103, 827 (2013)
Machado NRCF, Miotto DMM, Fuel, 84(18), 2289 (2005)
Musyoka NM, Petrik LF, Fatoba OO, Hums E, Miner. Eng., 53, 9 (2013)
Purnomo CW, Salim C, Hinode H, Microporous Mesoporous Mater., 162, 6 (2012)
Chen D, Hu X, Shi L, Cui Q, Wang H, Yao H, Appl. Clay Sci., 59-60, 148 (2012)
El-Naggar MR, El-Kamash AM, El-Dessouky MI, Ghonaim AK, J. Hazard. Mater., 154(1-3), 963 (2008)
Jha VK, Nagae M, Matsuda M, Miyake M, J. Environ. Manage., 90, 2507 (2009)
Izidoro JD, Fungaro DA, dos Santos FS, Wang SB, Fuel Process. Technol., 97, 38 (2012)
Terzano R, Spagnuolo M, Medici L, Dorrine W, Janssens K, Ruggiero P, Appl. Clay Sci., 35, 128 (2007)
Yaping Y, Xiaoqiang Z, Weilan Q, Mingwen W, Feul, 87, 1880 (2008)
Hollman GG, Steenbruggen G, Janssen-Jurkovicova M, Feul, 78, 1225 (1999)
Wang CF, Li JS, Wang LJ, Sun XY, J. Hazard. Mater., 155(1-2), 58 (2008)
Querol X, Moreno N, Umana JC, Alastuey A, Hernandez E, Lopez-Soler A, Plana F, Int. J. Coal Geol., 50(1-4), 413 (2002)
Kugbe J, Matsue N, Henmi T, J. Hazard. Mater., 164(2-3), 929 (2009)
http://www.petrotex.us/wp-content/uploads/2013/04/UOPManual.pdf (accessed Nov. 2017).
Seo JH, Beak CS, Kown WT, Ahn JW, Cho KH, J. Korean Inst. Resour. Recycl., 25(5), 14 (2016)

[1] http://news.kmib.co.kr/article/view.asp?arcid=0923702824&code=11131413&cp (accessed Nov. 2017).

[2] Belviso C, Cavalcante F. Lettino A, Fiore S, Appl. Clay Sci., 80-81, 162 (2013)

[3] Izidoro JD, Fungaro DA, Abbott JE, Wang SB, Fuel, 103, 827 (2013)

[4] Machado NRCF, Miotto DMM, Fuel, 84(18), 2289 (2005)

[5] Musyoka NM, Petrik LF, Fatoba OO, Hums E, Miner. Eng., 53, 9 (2013)

[6] Purnomo CW, Salim C, Hinode H, Microporous Mesoporous Mater., 162, 6 (2012)

[7] Chen D, Hu X, Shi L, Cui Q, Wang H, Yao H, Appl. Clay Sci., 59-60, 148 (2012)

[8] El-Naggar MR, El-Kamash AM, El-Dessouky MI, Ghonaim AK, J. Hazard. Mater., 154(1-3), 963 (2008)

[9] Jha VK, Nagae M, Matsuda M, Miyake M, J. Environ. Manage., 90, 2507 (2009)

[10] Izidoro JD, Fungaro DA, dos Santos FS, Wang SB, Fuel Process. Technol., 97, 38 (2012)

[11] Terzano R, Spagnuolo M, Medici L, Dorrine W, Janssens K, Ruggiero P, Appl. Clay Sci., 35, 128 (2007)

[12] Yaping Y, Xiaoqiang Z, Weilan Q, Mingwen W, Feul, 87, 1880 (2008)

[13] Hollman GG, Steenbruggen G, Janssen-Jurkovicova M, Feul, 78, 1225 (1999)

[14] Wang CF, Li JS, Wang LJ, Sun XY, J. Hazard. Mater., 155(1-2), 58 (2008)

[15] Querol X, Moreno N, Umana JC, Alastuey A, Hernandez E, Lopez-Soler A, Plana F, Int. J. Coal Geol., 50(1-4), 413 (2002)

[16] Kugbe J, Matsue N, Henmi T, J. Hazard. Mater., 164(2-3), 929 (2009)

[17] http://www.petrotex.us/wp-content/uploads/2013/04/UOPManual.pdf (accessed Nov. 2017).

[18] Seo JH, Beak CS, Kown WT, Ahn JW, Cho KH, J. Korean Inst. Resour. Recycl., 25(5), 14 (2016)