화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.4, 853-858, April, 2018
DOI10.1007/s11814-018-0003-2  Export Citation
Biosynthesized Au/TiO2@SBA-15 catalysts for selective oxidation of cyclohexane with O2
Fang Yao, Lixin Xu, Jili Luo1, Xiao Li, Yue An2, and Chao Wan†
  • College of Chemistry and Chemical Engineering, Anhui University of Technology, 59 Hudong Road, Ma’anshan 243002, China
  • 1Petro China Huabei Oilfield Company Gas Storage Management Service, 15 Battle Road, Renqiu 062550, China
  • 2College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China
E-mail:
A variety of TiO2@SBA-15 supporters with various TiO2 loadings were synthesized using a facile sol-gel method. Gold (Au)-based catalysts were prepared with an environmentally benign and economical bioreduction method via Cacumen Platycladi (CP) leaf extract and immobilized on various TiO2@SBA-15 supporters with different TiO2 loadings. The as-prepared biosynthesized Au catalysts were applied in the liquid-phase cyclohexane oxidation. The results showed that the Au nanoparticles were well-dispersed on TiO2@SBA-15, and the Au existed as Au0. These biosynthesized Au catalysts are promising for cyclohexane oxidation, achieving a turnover frequency up to 3,426 h.1 with a 14.1% cyclohexane conversion rate.
Keywords:Cyclohexane Oxidation;Biosynthesis;Nanocomposites;Au/TiO2@SBA-15;Oxygen
  1. Bhattacharjee S, Lee YR, Ahn WS, Korean J. Chem. Eng., 34(3), 701 (2017)
  2. Liu S, Liu Z, Kawi S, Korean J. Chem. Eng., 15(5), 510 (1998)
  3. Speight JG, Chemical and Process Design Handbook, McGraw-Hill, New York, 2185 (2002).
  4. Zhao R, Wang YQ, Guo YL, Liu XH, Zhang ZG, Wang YS, Zhan WC, Lu GZ, Green Chem., 8, 459 (2006)
  5. Santra C, Shah S, Mondal A, Pandey JK, Panda AB, Maity S, Chowdhury B, Microporous Mesoporous Mater., 223, 121 (2016)
  6. Dummer NF, Bawaked S, Hayward J, Jenkins R, Hutchings GJ, Catal. Today, 154(1-2), 2 (2010)
  7. Machado PMA, Lube LM, Tiradentes MDE, Fernandes C, Gomes CA, Stumbo AM, San Gil RAS, Visentin LC, Sanchez DR, Frescura VLA, Silva JSA, Horn AH, Appl. Catal. A: Gen., 507, 119 (2015)
  8. Huang G, Mo LQ, Cai JL, Cao X, Peng Y, Guo YA, Wei SJ, Appl. Catal. B: Environ., 162, 364 (2015)
  9. Shul’pin GB, Nesterov DS, Shul’pina LS, Pombeiro AJL, Inorg. Chim. Acta., 455, 666 (2017)
  10. Shul’pin GB, Catalysts, 6, 50 (2016)
  11. Karslyan EE, Shul’pina LS, Kozlov YN, Pombeiro AJL, Shul’pin GB, Catal. Today, 218-219, 93 (2013)
  12. Zhang PF, Lu HF, Zhou Y, Zhang L, Wu ZL, Yang SZ, Shi HL, Zhu QL, Chen YF, Dai S, Nat. Commun., 6, 8446 (2015)
  13. Liu X, Conte M, Sankar M, He Q, Murphy DM, Morgan D, Jenkins RL, Knight D, Whiston K, Kiely CJ, Hutchings GJ, Appl. Catal. A: Gen., 504, 373 (2015)
  14. Wu PP, Bai P, Lei ZB, Loh KP, Zhao XS, Microporous Mesoporous Mater., 141, 222 (2011)
  15. Wu K, Li BS, Han CY, Liu JJ, Appl. Catal. A: Gen., 479, 70 (2014)
  16. Khare S, Shrivastava P, J. Mol. Catal. A-Chem., 411, 279 (2016)
  17. Feng H, Elam JW, Libera JA, Pellin MJ, Stair PC, J. Catal., 269(2), 421 (2010)
  18. Gu JL, Huang Y, Elangovan SP, Li YS, Zhao WR, Toshio I, Yamazaki Y, Shi JL, J. Phys. Chem. C, 115, 21211 (2011)
  19. Fu Y, Zhan WC, Guo YL, Wang YQ, Liu XH, Guo Y, Wang YS, Lu GZ, Microporous Mesoporous Mater., 214, 101 (2015)
  20. Wu PP, Bai P, Yan ZF, Zhao GXS, Sci. Rep., 6, 18817 (2016)
  21. Sun ZG, Li G, Liu LP, Liu HO, Catal. Commun., 27, 200 (2012)
  22. Liu Y, Tsunoyama H, Akita T, Xie S, Tsukuda T, ACS Catal., 1, 2 (2011)
  23. Hereijgers BPC, Weckhuysen BM, J. Catal., 270(1), 16 (2010)
  24. Li L, Ji W, Au CT, Prog. Chem., 21, 1742 (2009)
  25. Haruta M, Gold Bull., 37, 27 (2004)
  26. Carabineiro SAC, Martins LMDRS, Avalos-Borja M, Buijnsters JG, Pombeiro AJL, Figueiredo JL, Appl. Catal. A: Gen., 467, 279 (2013)
  27. de Almeida MP, Martins LMDRS, Carabineiro SAC, Lauterbach T, Rominger F, Hashmi ASK, Pombeiro AJL, Figueiredo JL, Catal. Sci. Technol., 3, 305 (2013)
  28. Ma LY, Zhou JC, Zhao H, Chem. React. Eng. Technol., 3, 228 (2007)
  29. Xu LX, He CH, Zhu MQ, Fang S, Catal. Lett., 114(3-4), 202 (2007)
  30. Lu GM, Zhao R, Qian G, Qi YX, Wang XL, Suo JS, Catal. Lett., 97(3-4), 115 (2004)
  31. Duan XG, Liu WM, Yue LM, Fu W, Ha MN, Li J, Lu GZ, Dalton Trans., 44, 17381 (2015)
  32. Yu N, Ding Y, Lo AY, Huang SJ, Wu PH, Liu C, Yin D, Fu Z, Yin D, Hung CT, Lei Z, Liu SB, Microporous Mesoporous Mater., 143, 426 (2011)
  33. Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD, J. Am. Chem. Soc., 120(24), 6024 (1998)
  34. Huang JL, Lin LQ, Sun DH, Chen HM, Yang DP, Li QB, Chem. Soc. Rev., 44, 6330 (2015)
  35. Ghodake G, Lee DS, Korean J. Chem. Eng., 28(12), 2329 (2011)
  36. Zhan GW, Hong YL, Mbah VT, Huang JL, Ibrahim AR, Du MM, Li QB, Appl. Catal. A: Gen., 439, 179 (2012)
  37. Du MM, Zhan GW, Yang X, Wang HX, Lin WS, Zhou Y, Zhu J, Lin L, Huang JL, Sun DH, Jia LS, Li QB, J. Catal., 283(2), 192 (2011)
  38. Huang YQ, Ma Y, Cheng YW, Wang LJ, Li X, Appl. Catal. A: Gen., 495, 124 (2015)
  39. Annamalai J, Nallamuthu T, Appl. Nanoscience, 5, 603 (2015)
  40. Huang JL, Li QB, Sun DH, Lu YH, Su YB, Yang X, Wang HX, Wang YP, Shao WY, He N, Nanotechnology, 18, 105104 (2007)
  41. Abdelghany AR, Abdelrazek EM, Badr SI, Abdel-Aziz MS, Morsi MA, J. Saudi Chemical Society (2015), DOI:10.1016/j.jscs.2015.10.002.
  42. Wang ZH, Fu HF, Han DM, Gu FB, J. Mater. Chem. A, 2, 20374 (2014)
  43. Zhao Y, Baeza JA, Rao NK, Calvo L, Gilarranz MA, Li YD, Lefferts L, J. Catal., 318, 162 (2014)
  44. Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
  45. Yang J, Zhang J, Zhu L, Chen S, Zhang Y, Tang Y, Zhu Y, Li Y, J. Hazard. Mater. B, 137(1), 952 (2006)
  46. Peza-Ledesma CL, Escamilla-Perea L, Nava R, Pawelec B, Fierro JLG, Appl. Catal. A: Gen., 375(1), 37 (2010)
  47. Huang YQ, Ma Y, Cheng YW, Wang LJ, Li X, Catal. Commun., 72, 20 (2015)
  48. Hong YL, Jing XL, Huang JL, Sun DH, Odoom-Wubah T, Yang F, Du MM, Li QB, ACS Sustainable Chem. Eng., 2, 1752 (2014)
  49. Li XH, Zheng WL, Pan HY, Yu Y, Chen L, Wu P, J. Catal., 300, 9 (2013)
  50. Zhou JC, Yang XF, Wang YQ, Chen WJ, Catal. Commun., 46, 228 (2014)
  51. Chen Y, Wang JY, Li WZ, Ju MT, Mater. Lett., 159, 131 (2015)