화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.60, 91-101, April, 2018
DOI10.1016/j.jiec.2017.10.006  Export Citation
Highly active and reducing agent-free preparation of cost-effective NiO-based carbon nanocomposite and its application in reduction reactions under mild conditions
Somasundaram Saravanamoorthy, Ill-Min Chung1, Vanaraj Ramkumar2, Baskar Ramaganthan3, and Mayakrishnan Gopiraman1, †
  • Department of Chemistry, National Institute of Technology, Tiruchirappalli 620015, India
  • 1Department of Applied Bioscience, College of Life & Environment Science, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, South Korea
  • 2Department of Chemistry, Anna University, Chennai 600025, India
  • 3Department of Chemistry, Indian Institute of Technology, Chennai 600036, India
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Highly efficient and cost-effective NiO-based carbon nanocomposite (NiO/CNP) was prepared for the transfer hydrogenation of aromatic aldehydes and reduction of nitrophenols. Uniform dispersion of NiO nanoparticles, surface area of NiO/CNP (67 m2 g-1), chemical state and content of Ni in NiO/CNP (+2, 5.1 wt%) were confirmed. High rate constant (kapp) values of 4.2 x 10 -2 s -1 and 3.06 x 10 -2 s -1 were calculated for the NiO/CNP-catalyzed reduction of nitrophenols. The NiO/CNP demonstrated an excellent catalytic activity towards the transfer hydrogenation reactions under very mild reaction conditions. Chemoselectivity, heterogeneity, stability, reusability and scale reaction of the NiO/CNP system were tested.
Keywords:Carbon nanocomposites;NiO nanoparticles;Catalysis;Reduction reactions;Reusability
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