화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.59, 350-361, March, 2018
Humic acid and trihalomethane breakdown with potential by-product formations for atmospheric air plasma water treatment
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In this study an atmospheric air plasma reactor was studied for the degradation of HA and THMs in water. Plasma treatment showed significant breakdown efficacies for HA and THMs. At an applied voltage of 80 kV about 93% of HA and >70% of THMs were degraded after 15 min and 30 min treatment time respectively, with the degradation following a first order kinetic model. Plasma induced reactive species including nitrates and H2O2 were quantified in the treated water. The results of FTIR analysis revealed that the molecular structure of HA was altered by the plasma treatment, with a decrease in aromaticity observed.
  1. Alsheyab MA, Munoz AH, Desalination, 207(1-3), 179 (2007)
  2. Lee J, Lee D, Sohn J, Water Sci. Technol., 55, 307 (2007)
  3. Moncayo-Lasso A, Pulgarin C, Benitez N, Water Res., 42, 4125 (2008)
  4. Mosteo R, Miguel N, Martin-Muniesa S, Ormad MP, Ovelleiro JL, J. Hazard. Mater., 172(2-3), 661 (2009)
  5. Shafiee MRM, Taghavi L, A Review Article, vol. 68, World Academy of Science, Engineering and Technology, 2012.
  6. King WD, Marrett LD, Cancer Causes Control, 7, 596 (1996)
  7. Gallard H, von Gunten U, Water Res., 36, 65 (2002)
  8. Waller K, Swan SH, DeLorenze G, Hopkins B, Epidemiology, 9, 134 (1998)
  9. Swan SH, Waller K, Hopkins B, Windham G, Fenster L, Schaefer C, Neutra RR, Epidemiology, 9, 126 (1998)
  10. Richardson SD, TrAC Trends Anal. Chem., 22, 666 (2003)
  11. Singer PC, Association AWW, Formation and Control of Disinfection Byproducts in Drinking Water, AWWA, 1999.
  12. EPA, Drinking Water Guidance on Disinfection By-Products Advice Note No. 4. Version 2, Enivornmental Protection Agency, 2007.
  13. Wang Y, Wang Q, Gao BY, Yue QY, Zhao YX, Chem. Eng. J., 193, 59 (2012)
  14. Rauthula MS, Srivastava VC, Chem. Eng. J., 168(1), 35 (2011)
  15. Wu Y, Zhou S, Qin F, Lai Y, Peng H, Huan jing ke xue = Huanjing kexue/[bian ji, Zhongguo ke xue yuan huan jing ke xue wei yuan hui Huan jing ke xue bian ji wei yuan hui.] 31, 996 (2010).
  16. Qiao S, Sun D, Tay J, Easton C, Water Sci. Technol., 47, 211 (2003)
  17. Prisciandaro M, Salladini A, Barba D, Chem. Eng. Trans. Ser., 14, 437 (2008)
  18. Fan HJ, Chiu T, Yang HS, Chen WC, Furuya E, J. Environ. Eng. Manag., 17, 325 (2007)
  19. Wang YH, Chen KC, Chen CR, Catal. Today, 216, 261 (2013)
  20. Cuetos MJ, Gomez X, Otero M, Moran A, Biochem. Eng. J., 40, 99 (2008)
  21. Porwal HJ, Mane AV, Velhal SG, Water Resour. Ind., 9, 1 (2015)
  22. Nan C, Tingting M, Kuixiao L, Zhang Y, Min Y, J. Environ. Sci., 21, 409 (2009)
  23. Jiang B, Zheng JT, Qiu S, Wu MB, Zhang QH, Yan ZF, Xue QZ, Chem. Eng. J., 236, 348 (2014)
  24. Sarangapani C, Dixit Y, Milosavljevic V, Bourke P, Sullivan C, Cullen P, Water Sci. Technol., 75, 207 (2017)
  25. Sarangapani C, O’Toole G, Cullen P, Bourke P, Innov. Food Sci. Emerg. Technol. (2017) 1466, doi:http://dx.doi.org/10.1016/j.ifset.2017.02.012.
  26. Sarangapani C, Misra N, Milosavljevic V, Bourke P, O’Regan F, Cullen P, J. Water Process Eng., 9, 225 (2016)
  27. Devi Y, Thirumdas R, Sarangapani C, Deshmukh R, Annapure U, Food Control, 77, 187 (2017)
  28. Ziuzina D, Patil S, Cullen PJ, Keener KM, Bourke P, J. Appl. Microbiol., 114(3), 778 (2013)
  29. Thirumdas R, Sarangapani C, Annapure US, Food Biophys, 10, 1 (2015)
  30. Bertran SE, Jover E, Bayona TJM, Erra SP, Molina MR, Reyes CC, (2010). Method for removing trihalomethanes and/or emerging pollutants using plasma, Google Patents.
  31. Wang T, Qu G, Ren J, Yan Q, Sun Q, Liang D, Hu S, Water Res., 89, 28 (2016)
  32. Panorel I, Kornev I, Hatakka H, Preis S, Water Sci. Technol., 11, 238 (2011)
  33. Fuhr JR, Kelleher DE, Martin WC, Musgrove A, Sugar J, Wiese WL, Reader, J. (1999). NIST Atomic Spectra Database. Version 2.0, March 1999, NIST Physical Reference Data.
  34. Jiang B, Zheng J, Liu Q, Wu M, Chem. Eng. J., 204-206, 32 (2012)
  35. Boehm D, Heslin C, Cullen PJ, Bourke P, Sci. Rep., 6 (2016)
  36. Shao T, Zhang C, Long KH, Zhang DD, Wang J, Yan P, Zhou YX, Appl. Surf. Sci., 256(12), 3888 (2010)
  37. Tao S, Kaihua L, Cheng Z, Ping Y, Shichang Z, Ruzheng P, J. Phys. D-Appl. Phys., 41, 215203 (2008)
  38. Shao T, Zhang C, Yu Y, Fang Z, Yan P, Europhys. Lett., 97, 55005 (2012)
  39. Gao LH, Sun L, Wan SG, Yu ZB, Li MJ, Chem. Eng. J., 228, 790 (2013)
  40. Lu N, Li J, Wang XX, Wang TC, Wu Y, Plasma Chem. Plasma Process., 32(1), 109 (2012)
  41. Reddy PMK, Subrahmanyam C, Ind. Eng. Chem. Res., 51(34), 11097 (2012)
  42. Jiang B, Zheng JT, Liu Q, Wu MB, Chem. Eng. J., 204, 32 (2012)
  43. Magureanu M, Piroi D, Mandache NB, David V, Medvedovici A, Parvulescu VI, Water Res., 44, 3445 (2010)
  44. Reddy PMK, Raju BR, Karuppiah J, Reddy EL, Subrahmanyam C, Chem. Eng., 217, 41 (2013)
  45. Selcuk H, Bekbolet M, Chemosphere, 73, 854 (2008)
  46. Edzwald JK, Becker WC, Wattier KL, Am. Water Works Assoc., 122 (1985).
  47. Kerc A, Bekbolet M, Saatci AM, Int. J. Photoenergy, 5, 75 (2003)
  48. Korshin GV Li CW, Benjamin MM, Water Res., 31, 1787 (1997)
  49. Bruggeman P, Degroote J, Leys C, Vierendeels J, Institute of Plasma Physics AS CR Prague, 859 (2007).
  50. Bruggeman P, Graham L, Degroote J, Vierendeels J, Leys C, J. Phys. D-Appl. Phys., 40, 4779 (2007)
  51. Willberg D, Lang P, Hochemer R, Kratel A, Hoffmann M, Environ. Sci. Technol., 30, 2526 (1996)
  52. Lukes P, Appleton AT, Locke BR, IEEE Trans. Ind. Appl., 40, 60 (2004)
  53. Su ZZ, Ito K, Takashima K, Katsura S, Onda K, Mizuno A, J. Phys. D-Appl. Phys., 35, 3192 (2002)
  54. Grabowski L, Van Veldhuizen E, Pemen A, Rutgers W, Plasma Sources Sci. Technol., 16, 226 (2007)
  55. Lopez A, Benbelkacem H, Pic JS, Debellefontaine H, Environ. Technol., 25, 311 (2004)
  56. Huang FM, Chen L, Wang HL, Yan ZC, Chem. Eng. J., 162(1), 250 (2010)
  57. Li J, Sato M, Ohshima T, Thin Solid Films, 515(9), 4283 (2007)
  58. Sun B, Sato M, Clements JS, J. Electrostat., 39, 189 (1997)
  59. Mededovic S, Locke BR, Ind. Eng. Chem. Res., 46(9), 2702 (2007)
  60. Attri P, Kim YH, Park DH, Park JH, Hong YJ, Uhm HS, Kim KN, Fridman A, Choi EH, Sci. Rep., 5, 9332 (2015)
  61. Tahara M, Okubo M, Proc. 2012 Joint Electrostatics Conference, Detection of Free Radicals Produced by a Pulsed Streamer Corona Discharge in Solution Using Electron Spin Resonance, vol. 102017.
  62. Muruganandham M, Swaminathan M, Dyes Pigment., 62, 269 (2004)
  63. Miao HF, Tao WY, J. Chem. Technol. Biotechnol., 83(3), 336 (2008)
  64. Hu Y, Bai Y, Yu H, Zhang C, Chen J, Bull. Environ. Contam. Toxicol., 91, 314 (2013)
  65. Li S, Ma X, Liu L, Cao X, RSC Adv., 5, 1902 (2015)
  66. Sarangapani C, Danaher M, Tiwari B, Lu P, Bourke P, Cullen PJ, Chem. Eng. J., 326, 700 (2017)
  67. Misra NN, Pankaj SK, Walsh T, O'Regan F, Bourke P, Cullen PJ, J. Hazard. Mater., 271, 33 (2014)
  68. Cullen PJ, Misra N, Han L, Bourke P, Keener K, O’Donnell C, Moiseev T, Mosnier JP, Milosavljevic V, IEEE Trans. Plasma Sci., 42, 2368 (2014)
  69. Brisset JL, Hnatiuc E, Plasma Chem. Plasma Process., 32(4), 655 (2012)
  70. Lu P, Boehm D, Bourke P, Cullen PJ, Plasma Process. Polym., 14(August ) (2017)
  71. Brisset JL, Pawlat J, Plasma Chem. Plasma Process., 36(2), 355 (2016)
  72. Brisset JL, Benstaali B, Moussa D, Fanmoe J, Njoyim-Tamungang E, Plasma Sources Sci. Technol., 20, 034021 (2011)
  73. Lukes P, Dolezalova E, Sisrova I, Clupek M, Plasma Sources Sci. Technol., 23, 015019 (2014)
  74. Staehelin J, Hoigne J, Environ. Sci. Technol., 16, 676 (1982)
  75. Kim KS, Kam SK, Mok YS, Chem. Eng. J., 271, 31 (2015)
  76. Lumsdon DG, Fraser AR, Environ. Sci. Technol., 39, 6624 (2005)
  77. Qin X, Liu F, Wang G, Huang G, Environ. Earth Sci., 73, 4011 (2015)
  78. Rodriguez FJ, Schlenger P, Garcia-Valverde M, Sci. Total Environ., 541, 623 (2016)
  79. Reddy PMK, Mahammadunnisa S, Subrahmanyam C, Chem. Eng. J., 238, 157 (2014)
  80. Tang WZ, Tassos S, Water Res., 31, 1117 (1997)
  81. Okuno H, Yim B, Mizukoshi Y, Nagata Y, Maeda Y, Ultrason. Sonochem., 7, 261 (2000)
  82. Adewuyi YG, Ind. Eng. Chem. Res., 40(22), 4681 (2001)
  83. Shemer H, Narkis N, Isr. J. Chem., 46, 27 (2006)
  84. Chin A, Berube P, Water Res., 39, 2136 (2005)
  85. Verma K, Gupta D, Gupta A, J. Environ. Chem. Eng., 4, 3021 (2016)
  86. Patoczka J, Tyrrell P, Wynne M, Proc. Water Environ. Fed., 2011, 189 (2011)
  87. Vranitzky R, Lahnsteiner J, Jaques A, Va Tech Wabah, R&D Process Engineering, Siemensstrasse, 89 (2005).