화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 242-250, March, 2018
DOI10.1016/j.jiec.2017.10.029  Export Citation
Mixed conducting molybdenum doped BSCF materials
E.V. Shubnikova1, O.A. Bragina1, and A.P. Nemudry1, 2, †
  • 1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of Russian Academy of Sciences, 630128 Novosibirsk, Russia, Russian Federation
  • 2Novosibirsk State University, 630090 Novosibirsk, Russia, Russian Federation
E-mail:
This work discusses the effect of partial substitution of cobalt in Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) by Mo (VI) cations on the crystal structure, microstructure and transport properties of doped materials. Ba0.5Sr0.5Co0.8-xMoxFe0.2O3-δ (BSCFMx) samples possess specific microstructure consisting of double perovskite domains distributed in the cubic perovskite matrix that results in the suppression of undesirable ≪cubic.hexagonal≫ phase transition at x ≥ 0.02. Doped BSCFMx perovskites demonstrate high oxygen permeability, improved CO2 tolerance, enhanced electrical conductivity and chemical compatibility with Ce0.8Gd0.2O2-δ electrolyte that allows to consider them as promising candidates both for oxygen transport membranes and cathodes for intermediate temperature SOFC.
Keywords:Oxygen deficient perovskite;Air separation;Hollow fiber membrane;Solid oxide fuel cell;Cathode materials;Electrical conductivity;Thermal expansion
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