화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 208-217, March, 2018
DOI10.1016/j.jiec.2017.10.025  Export Citation
Novel coal and siloxane based surfactants: Bola polysiloxanes modified with butynediol-ethoxylate and their properties
Pengxiao Fang, Yanyun Bai, Xiaoyuan Ma, Xiumei Tai, Wanxu Wang, and Guoyong Wang†
  • China Research Institute of Daily Chemical Industry, Taiyuan 030001, PR China
E-mail:
Novel polysiloxane amphiphiles obtained by introducing coal-based amphiphiles (butynediol ethoxylate) into polysiloxanes based on hydrosilylation reaction by two steps: first, synthesizing hydride terminated polysiloxane with different degree of polymerization (HTP); second, butynediolethoxylate was grafted on hydride terminated polysiloxane at terminals to get bola coal-based polysiloxane amphiphiles (EO-PSi-EO). In our work, EO-PSi-EO were compared together to investigate the impacts of different ratios of hydrophilic and hydrophobic groups on its properties. A conclusion was obtained from the work that EO-PSi-EO with various hydrophobic backbones have low surface tension, rich aggregate behavior, excellent wetting property and low foam.
Keywords:Coal-based amphiphiles;Butynediol-ethoxylate;Hydride terminated polysiloxane;Bola coal-based polysiloxane amphiphiles
  1. Berson S, Viet D, Halila S, Driguez H, Fleury E, Hamaide T, Macromol. Chem. Phys., 209, 1814 (2008)
  2. Hill RM, Silicone Surfactants, Marcel Dekker, 1999.
  3. Verdia P, Gunaratne HQN, Goh TY, Jacquemin J, Blesic M, Green Chem., 18, 1234 (2016)
  4. Laubie B, Bonnafous E, Desjardin V, Germain P, Fleury E, Sci. Total Environ., 454-455, 199 (2013)
  5. Wang GY, Du ZP, Zhang W, Cao QY, Tenside Surfact. Deterg., 46, 214 (2009)
  6. Rosen MJ, Colloids Surf., 40, 347 (2004)
  7. Owen MJ, Dvornic PR, Adv. Silicon Sci., 4, 375 (2012)
  8. Tadros TF, Applied Surfactants: Principles and Applications, John Wiley & Sons, 2006.
  9. Wang GY, Du ZP, Li QX, Zhang W, J. Phys. Chem. B, 114(20), 6872 (2010)
  10. Wang GY, Qu WS, Du ZP, Cao QY, Li QX, J. Phys. Chem. B, 115(14), 3811 (2011)
  11. Hill RM, Curr. Opin. Colloid Interface Sci., 7, 255 (2002)
  12. Contributio GOW, Polyurethane Handbook, Hanser Publications, 1985.
  13. Zhang GD, Xiang-Yang LI, Deterg. Cosmet., 6, 29 (2006)
  14. Holmberg K, Novel Surfactants: Preparation, Applications, and Biodegrad-ability, Marcel Dekker, 1998.
  15. Xiao-Hua XU, Jiao QZ, Zhang Q, Zhang ZJ, Agrochemicals, 4, 235 (2007)
  16. Zhang P, Wang K, Chen J, Wang JG, J. Jilin Inst. Chem. Technol., 28(01), 1 (2011)
  17. Hou Z, Kan C, J. Surfact. Deterg., 18, 517 (2015)
  18. Hou Z, Yang B, Zhang D, Xu Z, Kan C, J. Surfact. Deterg., 19, 739 (2016)
  19. Han F, Zhang G, J. Surfact. Deterg., 7, 175 (2004)
  20. Yu Q, Yin H, Chin. J. Chem. Eng., 14(4), 555 (2006)
  21. Meister A, Blume A, Curr. Opin. Colloid Interface Sci., 12, 138 (2007)
  22. Ghosh S, An X, Shah R, Rawat D, Dave B, Kar S, Talapatra S, J. Phys. Chem. C, 116, 20688 (2012)
  23. Lee JH, Ahn J, Masuda M, Jaworski J, Jung JH, Langmuir, 29(44), 13535 (2013)
  24. Iwaura R, Iizawa T, Minamikawa H, Ohnishikameyama M, Shimizu T, Small, 6, 1131 (2010)
  25. Wahab M, Schiller P, Schmidt R, Mogel HJ, Langmuir, 26(5), 2979 (2010)
  26. Zakharova L, Syakaev V, Voronin M, Semenov V, Valeeva F, Ibragimova A, Bilalov A, Giniyatullin R, Latypov S, Reznik V, Konovalov A, J. Colloid Interface Sci., 342(1), 119 (2010)
  27. Jung JH, Rim JA, Cho EJ, Lee SJ, Jeong IY, Kameda N, Masuda M, Shimizu T, Tetrahedron, 63, 7449 (2007)
  28. Kwak J, Lee SY, Langmuir, 29(14), 4477 (2013)
  29. Kwak J, Park SI, Lee SY, Colloids Surf. B: Biointerfaces, 102, 70 (2013)
  30. Muzzalupo R, Trombino S, Iemma F, Puoci F, La MC, Picci N, Colloids Surf. B: Biointerfaces, 46, 78 (2005)
  31. Putzien S, Nuyken O, Kuhn FE, Prog. Polym. Sci, 35, 687 (2010)
  32. Vadala ML, Rutnakornpituk M, Zalich MA, St Pierre TG, Riffle JS, Polymer, 45(22), 7449 (2004)
  33. Rutnakornpituk M, Eur. Polym. J., 41, 1043 (2005)
  34. Chung DW, Kim JP, Kim D, Lim J, J. Ind. Eng. Chem., 12(5), 783 (2006)
  35. Srividhya M, Chandrasekar K, Baskar G, Reddy BSR, Polymer, 48(5), 1261 (2007)
  36. Chung DW, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 336, 35 (2009)
  37. Mathias JH, Rosen MJ, Davenport L, Langmuir, 17(20), 6148 (2001)
  38. Sakai K, Umezawa S, Tamura M, Takamatsu Y, Tsuchiya K, Torigoe K, Ohkubo T, Yoshimura T, Esumi K, Sakai H, Abe M, J. Colloid Interface Sci., 318(2), 440 (2008)
  39. Wang GY, Qu WS, Du ZP, Wang WX, Li QX, J. Phys. Chem. B, 117(11), 3154 (2013)
  40. Wang GY, Li P, Du ZP, Wang WX, Li GJ, Langmuir, 31(30), 8235 (2015)
  41. Czajka A, Hazell G, Eastoe J, Deterg. Cosmet., 31, 8205 (2015)
  42. Wang B, Preparation and Application of Organosilicone Surfactant, Guangdong Chemical Industry, 2013.
  43. Li P, Wang W, Du Z, Wang G, Li E, Li X, Colloids Surf. A: Physicochem. Eng. Asp., 450, 52 (2014)
  44. Wang G, Li X, Du Z, Li E, Li P, J. Mol. Liq., 197, 197 (2014)
  45. Schuster T, Krumpfer JW, Schellenberger S, Friedrich R, Klapper M, Mullen K, J. Colloid Interface Sci., 428, 276 (2014)
  46. Yu H, Hua P, Zhu G, Liu J, Kong D, Liu Q, Shiyou Huagong/Petrochem. Technol., 68 (2017).
  47. Kuo PL, Hou SS, Teng CK, Liang WJ, Colloid Polym. Sci., 279, 286 (2001)
  48. Liu G, Wang C, Zhu H, Chen S, Wu X, J. Dispers. Sci. Technol., 38, 699 (2016)
  49. Du Z, Wang L, Wang G, Wang S, Colloids Surf. A: Physicochem. Eng. Asp., 381, 55 (2011)
  50. Chandler D, Nature, 437, 640 (2005)
  51. Feng C, Chen L, Yan Z, Du Z, J. Dispersion Sci. Technol., 37 (2016)
  52. Ivanova NA, Starov VM, Curr. Opin. Colloid Interface Sci., 16, 285 (2011)
  53. Halverson JD, Maldarelli C, Couzis A, Koplik J, Chem. Eng. Sci., 64(22), 4657 (2009)
  54. Gaofeng LI, Coltd CSG, Low Foam Surfactant and Application in Industrial Cleaning, Cleaning World, 2015.
  55. Shi L, Zhang SF, Progress on Foaming Properties of Surfactants in Flotation Deinking, Hlongjang L & Ar, 2010.