화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 134-140, March, 2018
DOI10.1016/j.jiec.2017.10.016  Export Citation
Cu/Al and Cu/Cr based layered double hydroxide nanoparticles as adsorption materials for water treatment
Stefan Berner, Paulo Araya, Joseph Govan, and Humberto Palza†
  • Departamento de Ingeniería Química y Biotecnología, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Santiago, Chile
E-mail:
Cu/Al and Cu/Cr layered double hydroxides (LDH) were synthesized using a simple co-precipitation method at room temperature. These particles were further modified by Co+2 incorporation, and calcined at 500 °C for synthesis of layered double oxides (LDO). The LDH crystallinity or these samples highly depended on the composition, with Cu/Al-LDH presenting much higher order than Cu/Cr-LDH. High values of methyl orange adsorption were measured especially after calcination. For instance, Cu/Al and Cu/Co/Al LDH exhibited maximum monolayer adsorption capacities of 313 and 240 mg/g, respectively, meanwhile the same particles transformed into LDO presented values of 780 and 583 mg/g.
Keywords:Layered double hydroxides;Adsorption;Layered double oxides
  1. Fard NE, Fazaeli R, Int. J. Chem. Kinet., 48, 691 (2016)
  2. Robati D, Mirza B, Rajabi M, Moradi O, Tyagi I, Agarwal S, Gupta VK, Chem. Eng. J., 284, 687 (2016)
  3. Houas A, Lachheb H, Ksibi M, Elaloui E, Guillard C, Herrmann JM, Appl. Catal. B: Environ., 31(2), 145 (2001)
  4. Lachheb H, Puzenat E, Houas A, Ksibi M, Elaloui E, Guillard C, Herrmann JM, Appl. Catal. B: Environ., 39(1), 75 (2002)
  5. Shah B, Shah A, Shah P, Arch. Appl. Sci., 3, 327 (2011)
  6. Yang Z, Wang F, Zhang C, Zeng G, Tan X, Yu Z, Zhong Y, Wang H, Cui F, RSC Adv., 6, 79415 (2016)
  7. Evans DG, Slade RCT, Struct. Bond., 119, 1 (2006)
  8. Zhao Y, Jia X, Waterhouse GIN, Wu LZ, Tung CH, O’Hare D, Zhang T, Adv. Energy Mater., 6, 150197 (2016)
  9. Shao MF, Han JB, Wei M, Evans DG, Duan X, Chem. Eng. J., 168(2), 519 (2011)
  10. Chowdhury PR, Bhattacharyya KG, Photochem. Photobiol. Sci., 16, 835 (2017)
  11. Lv M, Liu H, J. Solid State Chem., 227, 232 (2015)
  12. Tian L, Zhao YF, He S, Wei M, Duan X, Chem. Eng. J., 184, 261 (2012)
  13. Parida K, Mohapatra L, Baliarsingh N, J. Phys. Chem., 116, 22417 (2012)
  14. Kim S, Fahel J, Durand P, Andre E, Carteret C, Eur. J. Inorg. Chem., 669 (2017).
  15. Xia SJ, Zhang XF, Zhou XB, Meng Y, Xue JL, Ni ZM, Appl. Catal. B: Environ., 214, 78 (2017)
  16. Darmograi G, Prelot B, Layrac G, Tichit D, Martin-Gassin G, Salles F, Zajac J, J. Phys. Chem., 119, 23388 (2015)
  17. Lu L, Li J, Ng DHL, Yang P, Song P, Zuo M, J. Ind. Eng. Chem., 46, 315 (2016)
  18. Ai L, Zhang C, Meng L, J. Chem. Eng. Data, 4217 (2011).
  19. Guzman-Vargas A, Lima E, Uriostegui-Ortega GA, Oliver-Tolentino MA, Rodriguez EE, Appl. Surf. Sci., 363, 372 (2016)
  20. Kameda T, Uchiyama T, Yoshioka T, New J. Chem., 39, 6315 (2015)
  21. Zou Y, Wang X, Chen Z, Yao W, Ai Y, Liu Y, Hayat T, Alsaedi A, Alharbi NS, Wang X, Environ. Pollut., 219, 107 (2016)
  22. Zou Y, Wang X, Ai Y, Liu Y, Li J, Ji Y, Wang X, Environ. Sci. Technol., 50, 3658 (2016)
  23. Liu X, Li J, Huang Y, Wang X, Zhang X, Wang X, Environ. Sci. Technol., 51, 6156 (2017)
  24. Wang J, Li YS, Chen WY, Peng JX, Hu J, Chen ZS, Wen T, Lu SS, Chen YT, Hayat T, Ahmad B, Wang XK, Chem. Eng. J., 309, 445 (2017)
  25. Kowalik P, Konkol M, Kondracka M, Prochniak W, Bicki R, Wiercioch P, Appl. Catal. A: Gen., 464-465, 339 (2013)
  26. Zaghouane-Boudiaf H, Boutahala M, Arab L, Chem. Eng. J., 187, 142 (2012)
  27. Yao W, Yu SJ, Wang J, Zou YD, Lu SS, Ai YJ, Alharbi NS, Alsaedi A, Hayat T, Wang XK, Chem. Eng. J., 307, 476 (2017)
  28. Lei CS, Zhu XF, Zhu BC, Jiang CJ, Le Y, Yu JG, J. Hazard. Mater., 321, 801 (2017)
  29. Barrault J, Derouault A, Courtois G, Maissant JM, Dupin JC, Guimon C, Martinez H, Dumitriu E, Appl. Catal. A: Gen., 262(1), 43 (2004)
  30. Manivannan R, Pandurangan A, Appl. Clay Sci., 44, 137 (2009)
  31. Marcu IC, Tichit D, Fajula F, Tanchoux N, Catal. Today, 147(3-4), 231 (2009)
  32. Tanasoi S, Tanchoux N, Urda A, Tichit D, Sandulescu I, Fajula F, Marcu IC, Appl. Catal. A: Gen., 363(1-2), 135 (2009)
  33. Valente JS, Hernandez-Cortez J, Cantu MS, Ferrat G, Lopez-Salinas E, Catal. Today, 150(3-4), 340 (2010)
  34. Zhang LH, Li F, Evans DG, Duan X, J. Mater. Sci., 45(14), 3741 (2010)
  35. Turco M, Bagnasco G, Costantino U, Marmottini F, Montanari T, Ramis G, Busca G, J. Catal., 228(1), 43 (2004)
  36. Behrens M, Kasatkin I, Kuhl S, Weinberg G, Chem. Mater., 22, 386 (2010)
  37. Li S, Wang H, Li W, Wu X, Tanga W, Chen Y, Appl. Catal. B: Environ., 166-167, 260 (2015)
  38. Palza H, Saldias N, Arriagada P, Palma P, Sanchez J, JOM, 69, 1319 (2017)
  39. Long X, Wang Z, Xiao S, An Y, Yang S, Mater. Today, 19, 213 (2016)
  40. Goh KH, Lim TT, Dong Z, Water Res., 42, 1343 (2008)
  41. Costantino U, Marmottini F, Nocchetti M, Vivani R, Eur. J. Inorg. Chem., 1998, 1439 (1998)
  42. Teixeira TPF, Aquino SF, Pereira SI, Dias A, Braz. J. Chem. Eng., 31, 19 (2014)
  43. Yun SK, Pinnavaia TJ, Chem. Mater., 348 (1995).
  44. Baliarsingh N, Parida KM, Pradhan GC, Ind. Eng. Chem. Res., 53(10), 3834 (2014)
  45. Ruan XX, Chen YH, Chen H, Qian GR, Frost RL, Chem. Eng. J., 297, 295 (2016)
  46. Goh KH, Lim TT, Dong Z, Water Res., 42, 1343 (2008)
  47. Gregoire B, Ruby C, Carteret C, Cryst. Growth Des., 12, 4324 (2012)
  48. Al-Jaberi M, Naille S, Dossot M, Ruby C, J. Mol. Struct., 1102, 253 (2015)
  49. Zou Y, Liu Y, Wang X, Sheng G, Wang S, Ai Y, Ji Y, Liu Y, Hayat T, Wang X, ACS Sustain. Chem. Eng., 5, 3583 (2017)
  50. Li B, Zhang Y, Zhou X, Liu Z, Liu Q, Li X, J. Alloy. Compd., 673, 265 (2016)
  51. Orthman J, Zhu HY, Lu GQ, Sep. Purif. Technol., 31(1), 53 (2003)
  52. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T, Pure Appl. Chem., 57, 603 (1985)
  53. Yao W, Yu SJ, Wang J, Zou YD, Lu SS, Ai YJ, Alharbi NS, Alsaedi A, Hayat T, Wang XK, Chem. Eng. J., 307, 476 (2017)
  54. Teixeira TPF, Aquino SF, Pereira SI, Dias A, Braz. J. Chem. Eng., 31, 19 (2014)