화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.59, 99-107, March, 2018
Synthesis of silver/silver chloride/exfoliated graphite nano-photocatalyst and its enhanced visible light photocatalytic mechanism for degradation of organic pollutants
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Silver/silver chloride/exfoliated graphite (Ag/AgCl/EG) nano-photocatalyst was synthesized through precipitation and photoreduction processes. Afterwards, physicochemical properties of Ag/AgCl/EG were systematically studied by series of techniques. Results indicated that spherical-like Ag0 and AgCl with a diameter of 18.6 nm were deposited onto the surface of EG, resulting in the large surface area, strong visible absorbance and high charge separation efficiency. In addition, Ag/AgCl/EG exhibited high visible light photocatalytic (PC) activity for degradation of RhB (99.5%) and phenol (89.1%) solution. Also, the enhanced visible light PC mechanism was proposed and confirmed. Furthermore, Ag/AgCl/EG nanophotocatalyst performed good reusability even after six recycles utilization.
  1. Ratpukdi T, Siripattanakul S, Khan E, Water Res., 44, 3531 (2010)
  2. Li XY, Liu YX, Zheng LC, Dong MJ, Xue ZH, Lu XQ, Liu XH, Electrochim. Acta, 113, 170 (2013)
  3. Vellanki BP, Batchelor B, J. Hazard. Mater., 262, 348 (2013)
  4. Parrino F, Camera-Roda G, Loddo V, Palmisano G, Augugliaro V, Water Res., 50, 189 (2014)
  5. Nguyen-Le MT, Lee BK, RSC Adv., 6, 31347 (2016)
  6. Xu SC, Pan SS, Xu Y, Luo YY, Zhang YX, Li GH, J. Hazard. Mater., 283, 7 (2015)
  7. Hu XX, Hu C, Peng TW, Zhou XF, Qu JH, Environ. Sci. Technol., 44, 7058 (2010)
  8. Tsukamoto D, Shiraishi Y, Sugano Y, Ichikawa S, Tanaka S, Hirai T, J. Am. Ceram. Soc., 134, 6309 (2012)
  9. Li RH, Chen WX, Kobayashi H, Ma CX, Green Chem., 10, 212 (2010)
  10. Pirhashemi M, Habibi-Yangjeh A, J. Colloid Interface Sci., 491, 218 (2017)
  11. Akhundi A, Habibi-Yangjeh A, Adv. Powder Technol., 28(2), 565 (2017)
  12. Naghizadeh-Alamdari S, Habibi-Yangjeh A, Pirhashemi M, Solid State Sci., 40, 111 (2015)
  13. Wang P, Huang BB, Zhang XY, Qin XY, Dai Y, Jin H, Wei JY, Whangbo MH, Chem. A Eur. J., 14, 10543 (2008)
  14. Chen XB, Burda C, J. Am. Chem. Soc., 130(15), 5018 (2008)
  15. Wang P, Huang BB, Qin XY, Zhang XY, Dai Y, Wei JY, Whangbo MH, Angew. Chem.-Int. Edit., 120, 8049 (2008)
  16. Qiao R, Mao MM, Hu EL, Zhong YJ, Ning JQ, Hu Y, Inorg. Chem., 54(18), 9033 (2015)
  17. Bao YC, Chen KZ, Nano Micro Lett., 8, 182 (2016)
  18. Mousavi M, Habibi-Yangjeh A, Abitorabi M, J. Colloid Interface Sci., 480, 218 (2016)
  19. Akhundi A, Habibi-Yangjeh A, Appl. Surf. Sci., 358, 261 (2015)
  20. Akhundi A, Habibi-Yangjeh A, Mater. Sci. Semicond. Process, 39, 162 (2015)
  21. Kang F, Zheng YP, Wang HN, Nishi Y, Inagaki M, Carbon, 40, 1575 (2002)
  22. Inagaki M, J. Mater. Res., 4, 1560 (1989)
  23. Cheng XW, Liu HL, Chen QH, Li JJ, Wang P, Carbon, 66, 450 (2014)
  24. Yu XJ, Wu J, Zhao Q, Cheng XW, Mater. Lett., 73, 11 (2012)
  25. Cheng XW, Yu XJ, Xing ZP, Appl. Surf. Sci., 258(19), 7644 (2012)
  26. Seredych M, Tamashausky AV, Bandosz TJ, Carbon, 46, 1241 (2008)
  27. Yang F, Liu DZ, Wang TY, Li W, Hu WP, Zhou XQ, J. Nanopart. Res., 18, 335 (2015)
  28. Dong QS, Jiao ZB, Yu HC, Ye JH, Bi YP, CrystEngComm, 16, 8317 (2014)
  29. Zhang H, Wang G, Chen D, Lv XJ, Li JH, Chem. Mater., 20, 6543 (2008)
  30. Hu C, Lan YQ, Qu JH, Hu XX, Wang AM, J. Phys. Chem. B, 110(9), 4066 (2006)
  31. Yao XX, Liu XH, Zhu D, Lu LD, Catal. Commun., 59, 151 (2015)
  32. Sakthivel S, Kisch H, Angew. Chem.-Int. Edit., 42, 4908 (2003)
  33. Wang P, Huang BB, Lou ZZ, Zhang XY, Qin XY, Dai Y, Zheng ZK, Wang XN, Chem. A Eur. J., 16, 538 (2010)
  34. Ao YH, Tang H, Wang PF, Wang C, Mater. Lett., 131, 74 (2014)
  35. Cheng XW, Cheng QF, Li B, Deng XY, Li JJ, Wang P, Zhang BQ, Liu HL, Wang XN, Electrochim. Acta, 186, 442 (2015)
  36. Li WJ, Li DZ, Zhang WJ, Hu Y, He YH, Fu XZ, J. Phys. Chem., 114, 2154 (2010)
  37. Lin YM, Li DZ, Hu JH, Xiao GC, Wang JX, Li WJ, Fu XZ, J. Phys. Chem., 116, 5764 (2012)
  38. Chen YM, Lu AH, Li Y, Zhang LS, Yip HY, Zhao HJ, An TC, Wong PK, Environ. Sci. Technol., 45, 5689 (2011)
  39. Ye LQ, Liu JY, Gong CQ, Tian LH, Peng TY, Zan L, ACS Catal., 2, 1677 (2012)
  40. An TC, An JB, Yang H, Li GY, Feng HX, Nie XP, J. Hazard. Mater., 197, 229 (2011)
  41. Wang XF, Li SF, Ma YQ, Yu HG, Yu JG, J. Phys. Chem., 115, 14648 (2011)
  42. Wang DF, Kako T, Ye JH, J. Am. Chem. Soc., 130(9), 2724 (2008)