화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 8-16, March, 2018
DOI10.1016/j.jiec.2017.09.053  Export Citation
Controlled deposition of MOFs by dip-coating in thin film nanocomposite membranes for organic solvent nanofiltration
Lilian Sarango1, 2, Lorena Paseta1, Marta Navarro1, Beatriz Zornoza1, and Joaquín Coronas1, †
  • 1Chemical and Environmental Engineering Department and Instituto de Nanociencia de Aragón (INA), Universidad de Zaragoza, 50018 Zaragoza, Spain, Korea
  • 2Electronics Engineering Career, Salesian Polytechnic University, Cuenca, Ecuador
E-mail:
ZIF-8 and ZIF-67 particles, with sizes of 70±10 nm and 240±40 nm, respectively, were deposited by dip-coating on top of polyimide P841 asymmetric supports. In the best conditions, this gives rise to a MOF (metal-organic framework) monolayer which remains on the polyimide support during the interfacial polymerization of polyamide carried out to produce a thin film nanocomposite membrane for organic solvent nanofiltration (OSN). This method is simple, shorter and is environmentally friendly, since no excess MOF is lost during the interfacial polymerization, exhibiting good OSN results: dye rejection of 90% together with a high methanol permeance of 8.7 L m-2 h-1 bar-1.
Keywords:Dip-coating,Thin film nanocomposite membrane;Organic solvent nanofiltration;Metal-organic framework;Zeolitic imidazolate framework
  1. Marchetti P, Solomon MFJ, Szekely G, Livingston AG, Chem. Rev., 114(21), 10735 (2014)
  2. Wu MB, Lv Y, Yang HC, Liu LF, Zhang X, Xu ZK, J. Membr. Sci., 515, 238 (2016)
  3. Wen P, Chen YB, Hu XY, Cheng BW, Liu DQ, Zhang YF, Nair S, J. Membr. Sci., 535, 208 (2017)
  4. Sorribas S, Gorgojo P, Tellez C, Coronas J, Livingston AG, J. Am. Chem. Soc., 135(40), 15201 (2013)
  5. Wang CB, Li ZY, Chen JX, Li Z, Yin YH, Cao L, Zhong YL, Wu H, J. Membr. Sci., 523, 273 (2017)
  6. Zornoza B, Martinez-Joaristi A, Serra-Crespo P, Tellez C, Coronas J, Gascon J, Kapteijn F, Chem. Commun., 47, 9522 (2011)
  7. Duan JT, Pan YC, Pacheco F, Litwiller E, Lai ZP, Pinnau I, J. Membr. Sci., 476, 303 (2015)
  8. Dong XL, Lin YS, Chem. Commun., 49, 1196 (2013)
  9. Solomon MFJ, Bhole Y, Livingston AG, J. Membr. Sci., 423, 371 (2012)
  10. Campbell J, Burgal JD, Szekely G, Davies RP, Braddock DC, Livingston A, J. Membr. Sci., 503, 166 (2016)
  11. Razali M, Kim JF, Attfield M, Budd PM, Drioli E, Lee YM, Szekely G, Green Chem., 17, 5196 (2015)
  12. Hermans S, Marien H, Van Goethem C, Vankelecom IFJ, Curr. Opin. Chem. Eng., 8, 45 (2015)
  13. White LS, J. Membr. Sci., 205(1-2), 191 (2002)
  14. Soroko I, Lopes MP, Livingston A, J. Membr. Sci., 381(1-2), 152 (2011)
  15. Cadotte JE, ACS Symp. Ser., 269, 273 (1985)
  16. Vandezande P, Gevers LEM, Vankelecom IFJ, Chem. Soc. Rev., 37, 365 (2008)
  17. Paul M, Jons SD, Polymer, 103, 417 (2016)
  18. Jeong BH, Hoek EMV, Yan YS, Subramani A, Huang XF, Hurwitz G, Ghosh AK, Jawor A, J. Membr. Sci., 294(1-2), 1 (2007)
  19. Kim IC, Jegal J, Lee KH, J. Polym. Sci. B: Polym. Phys., 40(19), 2151 (2002)
  20. Kosaraju PB, Sirkar KK, J. Membr. Sci., 321(2), 155 (2008)
  21. Van Goethem C, Verbeke R, Hermans S, Bernstein R, Vankelecom IFJ, J. Mater. Chem., 4, 16368 (2016)
  22. Gevers LEM, Vankelecom IFJ, Jacobs PA, Chem. Commun., 2500 (2005).
  23. Gevers LEM, Vankelecom IFJ, Jacobs PA, J. Membr. Sci., 278(1-2), 199 (2006)
  24. Basu S, Maes M, Cano-Odena A, Alaerts L, De Vos DE, Vankelecom IFJ, J. Membr. Sci., 344(1-2), 190 (2009)
  25. Campbell J, Szekely G, Davies RP, Braddock DC, Livingston AG, J. Mater. Chem., 2, 9260 (2014)
  26. Wang L, Fang M, Liu J, He J, Deng L, Li J, Lei J, RSC Adv., 5, 50942 (2015)
  27. Wang LY, Fang MQ, Liu J, He J, Li JD, Lei JD, ACS Appl. Mater. Interfaces, 7, 24082 (2015)
  28. Brinker CJ, Frye GC, Hurd AJ, Ashley CS, Thin Solid Films, 201, 97 (1991)
  29. Park KS, Ni Z, Cote AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O’Keeffe M, Yaghi OM, Proc. Natl. Acad. Sci. U. S. A., 103, 10186 (2006)
  30. Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O'Keeffe M, Yaghi OM, Science, 319, 939 (2008)
  31. Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 21, 1410 (2009)
  32. Sun WZ, Zhai XS, Zhao L, Chem. Eng. J., 289, 59 (2016)
  33. Toh YHS, Lim FW, Livingston AG, J. Membr. Sci., 301(1-2), 3 (2007)
  34. Aragon FH, de Souza PEN, Coaquira JAH, Hidalgo P, Gouvea D, Phys. Rev. B, 407, 2601 (2012)
  35. Benito J, Fenero M, Sorribas S, Zornoza B, Msayib KJ, McKeown NB, Tellez C, Coronas J, Gascon I, Colloids Surf. A: Physicochem. Eng. Asp., 470, 161 (2015)
  36. Quere D, Physica A, 313, 32 (2002)
  37. Volkov AV, Parashchuk VV, Stamatialis DF, Khotimsky VS, Volkov VV, Wessling M, J. Membr. Sci., 333(1-2), 88 (2009)
  38. Roy S, Ntim SA, Mitra S, Sirkar KK, J. Membr. Sci., 375(1-2), 81 (2011)
  39. Yang XJ, Livingston AG, dos Santos LF, J. Membr. Sci., 190(1), 45 (2001)
  40. Echaide-Gorriz C, Sorribas S, Tellez C, Coronas J, RSC Adv., 6, 90417 (2016)
  41. Cacho-Bailo F, Matito-Martos I, Perez-Carbajo J, Etxeberria-Benavides M, Karvan O, Sebastian V, Calero S, Tellez C, Coronas J, Chem. Sci., 8, 325 (2017)
  42. Van der Bruggen B, Schaep J, Wilms D, Vandecasteele C, J. Membr. Sci., 156(1), 29 (1999)
  43. Park HS, Kang SW, Tortora L, Nastishin Y, Finotello D, Kumar S, Lavrentovich OD, J. Phys. Chem. B, 112(51), 16307 (2008)
  44. Liu MH, Wu DH, Yu SC, Gao CJ, J. Membr. Sci., 326(1), 205 (2009)
  45. Lind ML, Ghosh AK, Jawor A, Huang XF, Hou W, Yang Y, Hoek EMV, Langmuir, 25(17), 10139 (2009)
  46. Echaide-Gorriz C, Navarro M, Tellez C, Coronas J, Dalton Trans., 46, 6244 (2017)