Al as a cheap and air-stable metal material has been widely applied to polymer solar cells (PSCs) as an efficient electrode. However, there are few care whether Al is a right electrode in PSCs for longtime stability. The inverted PSCs with the structure of ITO/ZnO/PTB7-Th:PC71BM/MoO3/Metal electrode were fabricated and the performance and stability of inverted PSCs with Al and AgAl electrodes were investigated. PSCs with AgAl electrode got the highest PCE value of 9.3% without aging. While the PCE of PSCs with Al electrode can be gradually improved and reach the highest value of 7.8% after aging for 36 h, which is attributed to the formation of AlOx interlayer at the interface of MoO3/Al. PSCs with AgAl electrode still retained 69% of the initial PCE value and got 6.6% of PCE aging for 796 days, showing amazing stability. However, PSCs with Al electrode was dropped to 3.7% of PCE aging for 796 days due to the continuously increased thickness of AlOx. interlayer, which can greatly increase the series resistance of cells. PSCs with AgAl electrode can be further improved and reach 10.2% of PCE using AZO (Al doped ZnO) instead of ZnO and show better UV-light resistance. The enhanced stability of PSCs with AgAl electrode is attributed to the dense and limited thick AlOx. interlayer self-formed at the MoO3/AgAl interface due to the low content of Al. Our results demonstrated that Ag alloy electrode such as AgAl is a good strategy to accurately control the thickness of the metal oxidation interlayer, which can overcome the disadvantage of AI electrode and greatly improve the longtime stability of devices.