Powder Technology, Vol.322, 290-295, 2017
Transformation of waste crystalline silicon into submicro beta-SiC by multimode microwave sintering with low carbon emissions
This paper presents a novel method for the transformation of waste crystalline silicon, including waste polysilicon (photovoltaic industry), single crystal silicon (waste chip), and activated carbon (AC) into submicro beta-SiC in timescales of minutes using a multimode microwave rotary tube reactor under open-air conditions. This research addressed the difficult problem of microwave sintering temperature measurement by using light conducted by a quartz tube wall. The synthesis underwent a liquid-solid reaction at 1450 +/- 50 degrees C for 6-8 min, which is a noticeable improvement when compared to industrial processes, where a heating time of 30 h and temperatures of 2200-2400 degrees C are commonly needed. Theoretical calculations show that the new synthesis method for beta-SiC consumes 4.1-4.8 times less energy than modern production methods using quartz sand (SiO2) as the raw material, and CO2 emission using this method is reduced by 76-79%. (C) 2017 Published by Elsevier B.V.