Aseries of liquid crystalline supramolecular copolymers formed through hydrogen bonding has been created. These polymers composed of bis-benzoic acids and two of pyridyl species-a small rigid bispyridyl capable of forming a mesophase and a small, flexible bis pyridyl nonmesogenic disruptor species. It was found that the polymers display monotropic nematic character at high concentrations of disruptors - up to 75% inclusion. Smectic phases were observed in loadings up to 50%. It is believed that the structural similarities between themesogenic and non-mesogenic acceptors contributes significantly to the enhanced stability of the liquid crystalline phases at high composition.